meso-Tetra(3,4-dimethoxyphenyl) porphine

Product Number: T14597; CAS Number: 88422-69-9

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meso-Tetra(3,4-dimethoxyphenyl) porphine CAS: 88422-69-9 MDL:  MFCD00830316

Molecular weight: 854.94 g/mol

Molecular Formula: C52H46N4O8

CAS Number: 88422-69-9

Storage: Store at room temperature, protect from light.

Synonyms: 1,2-Dimethoxy-4-[7,12,17-tris(3,4-dimethoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1<3,6>.1<8,11>.1<13,16>]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaen-2-yl]benzene, 21H,23H-Porphine, 5,10,15,20-tetrakis(3,4-dimethoxyphenyl)- , 5,10,15,20-Tetrakis(3,4-dimethoxyphenyl)porphyrin, 5,10,15,20-Tetrakis(3,4-dimethoxyphenyl)porphyrin, 5,10,15,20-Tétrakis(3,4-diméthoxyphényl)porphyrine, 2,7,12,17-tetra(3,4-dimethoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1. 13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undec aene, 2,7,12,17-tetrakis(3,4-dimethoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.13,?.1?,11.113,1?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 88422-69-9, tetra(3,4-dimethoxyphenyl)porphyrin

Fields of Interest: Synthetic Porphyrins

Background: meso-Tetra(3,4-dimethoxyphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Adineh, et al. Fabrication and analysis of dye-sensitized solar cells (DSSCs) using porphyrin dyes with catechol anchoring groups. RSC Advances, 2016, vol. 6, # 18, p. 14512 – 14521. https://doi.org/10.1039/C5RA23584G

2.) Katona, et al. Triplet state spectroscopic studies on some 5,10,15,20-tetrakis(methoxyphenyl)porphyrins. Journal of Molecular Structure, 1998, vol. 450, # 1-3, p. 41 – 45. https://doi.org/10.1016/S0022-2860(98)00411-6

3.) Sergeeva, et al. Synthesis of hydroporphyrins based on comparative studies of palladium-catalyzed and non-catalyzed approaches. Tetrahedron, 2007, vol. 63, # 50, p. 12454 – 12464. https://doi.org/10.1016/j.tet.2007.09.030

4.) Marydasan, et al. In Vitro and in Vivo Demonstration of Human-Ovarian-Cancer Necrosis through a Water-Soluble and Near-Infrared-Absorbing Chlorin. Journal of Medicinal Chemistry, 2018, vol. 61, # 11, p. 5009 – 5019. https://doi.org/10.1021/acs.jmedchem.8b00460

5.) Shehzad, et al. Organic-Inorganic Hybrids Composed of Keggin-Type [PMo10V2O40]5- Anions and Porphyrins: The Synthesis, Characterization, and Influence of Porphyrin Substituents on Optical Nonlinearities. Journal of Physical Chemistry C, 2020, vol. 124, # 17, p. 9442 – 9450. https://doi.org/10.1021/acs.jpcc.0c00861

6.) Chen, et al. Energy Band Alignment and Redox-Active Sites in Metalloporphyrin-Spaced Metal-Catechol Frameworks for Enhanced CO2 Photoreduction. Angewandte Chemie – International Edition, 2022, vol. 61, # 1, art. no. E202111622. https://onlinelibrary.wiley.com/doi/epdf/10.1002/anie.202111622

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[88422-69-9]

Purity %

>95%

Smiles

COC1=C(OC)C=C(C=C1)C1=C2NC(C=C/2)=C(/C2=N/C(/C=C2)=C(C2=CC=C(N2)/C(=C2/C=CC1=N/2)C1=CC(OC)=C(OC)C=C1)C1=CC(OC)=C(OC)C=C1)C1=CC(OC)=C(OC)C=C1

Molecular Weight

854.944

Molecular Formula

C52H46N4O8

Functional Groups

Alkoxy, Ether, Methoxy

Porphyrin Family

A4 Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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