meso-Tetra(2,6-dimethoxyphenyl) porphine

meso-Tetra(2,6-dimethoxyphenyl) porphine CAS: 118762-56-4 MDL:  MFCD32668781

Molecular weight: 854.94 g/mol

Molecular Formula: C₅₂H₄₆N₄O₈

CAS Number: 118762-56-4

Storage: Store at room temperature, protect from light.

Synonyms: 1,3-Dimethoxy-2-[7,12,17-tris(2,6-dimethoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1<3,6>.1<8,11>.1<13,16>]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaen-2-yl]benzene, 21H,23H-Porphine, 5,10,15,20-tetrakis(2,6-dimethoxyphenyl)-, 5,10,15,20-Tetrakis(2,6-dimethoxyphenyl)porphyrin, 5,10,15,20-Tetrakis(2,6-dimethoxyphenyl)porphyrin, 5,10,15,20-Tétrakis(2,6-diméthoxyphényl)porphyrine, 118762-56-4, 2,7,12,17-tetrakis(2,6-dimethoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.13,?.1?,11.113,1?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene

Fields of Interest: Synthetic Porphyrins, Catalysis, Supramolecular Chemistry

Background: meso-Tetra(2,6-dimethoxyphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Marianov, et al. Resolving deactivation pathways of Co porphyrin-based electrocatalysts for CO₂ reduction in aqueous medium. ACS Catalysis, 2021, vol. 11, # 6, p. 3715 – 3729. https://doi.org/10.1021/acscatal.0c05092

2.) Bonnet, et al. Ligand Controls the Activity of Light-Driven Water Oxidation Catalyzed by Nickel(II) Porphyrin Complexes in Neutral Homogeneous Aqueous Solutions. Angewandte Chemie – International Edition, 2021, vol. 60, # 24, p. 13463 – 13469. https://doi.org/10.1002/anie.202103157

3.) Weng, et al. Electrochemical CO₂ Reduction to Hydrocarbons on a Heterogeneous Molecular Cu Catalyst in Aqueous Solution. Journal of the American Chemical Society, 2016, vol. 138, # 26, p. 8076 – 8079. https://doi.org/10.1021/jacs.6b04746

4.) Bhyrappa, et al. Hydrogen-bonded porphyrinic solids: Supramolecular networks of octahydroxy porphyrins. Journal of the American Chemical Society, 1997, vol. 119, # 36, p. 8492 – 8502. https://doi.org/10.1021/ja971093w

5.) Huang, et al. Diastereoselective and enantioselective cyclopropanation of alkenes catalyzed by cobalt porphyrins. Journal of Organic Chemistry, 2003, vol. 68, # 21, p. 8179 – 8184. https://doi.org/10.1021/jo035088o

6.) Monnereau, et al. Porphyrin macrocyclic catalysts for the processive oxidation of polymer substrates. Journal of the American Chemical Society, 2010, vol. 132, # 5, p. 1529 – 1531. https://doi.org/10.1021/ja908524x