meso-Tetra(2-methoxyphenyl) porphine

Product Number: U34635; CAS Number: 29114-94-1

$255.00$644.00

$255.00
$419.00
$644.00
SKU: U34635 Category:

meso-Tetra(2-methoxyphenyl) porphine CAS: 29114-94-1 MDL: MFCD01074424

Molecular weight: 734.84 g/mol

Molecular Formula: C48H38N4O4

CAS Number: 29114-94-1

Storage: Store at room temperature, protect from light

Synonyms: 21H,22H-Porphine, 5,10,15,20-tetrakis(2-methoxyphenyl)-, 5,10,15,20-Tetrakis(2-methoxyphenyl)porphyrin, 5,10,15,20-Tetrakis(2-methoxyphenyl)porphyrin, 5,10,15,20-Tétrakis(2-méthoxyphényl)porphyrine, 29114-94-1, 2-Methoxy-1-[7,12,17-tris(2-methoxyphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1<3,6>.1<8,11>.1<13,16>]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaen-2-yl]benzene, 5,10,15,20-tetrakis(2-methoxyphenyl)-21,22-dihydroporphyrin

Field of Interest: Synthetic Porphyrins, Catalysis, Porphyrin Cage Compounds

Background: meso-Tetra(2-methoxyphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. meso-Tetra(2-methoxyphenyl) porphine is sold as a mixture of atropisomers.

References: 

1.) Chen, et al. Mechanistic Studies on the Epoxidation of Alkenes by Macrocyclic Manganese Porphyrin CatalystsEuropean Journal of Organic Chemistry, 2022, vol. 2022, # 35, art. no. E202200280. 

2.) Shen, HM., Qi, B., Hu, MY. et al. Selective Solvent-Free and Additive-Free Oxidation of Primary Benzylic C–H Bonds with O2 Catalyzed by the Combination of Metalloporphyrin with N-HydroxyphthalimideCatal Lett 150, 3096–3111 (2020). https://doi.org/10.1007/s10562-020-03214-y

3.) Gilissen, et al. Rapid and scalable synthesis of chiral porphyrin cage compounds. Tetrahedron, 2019, vol. 75, # 33, p. 4640 – 4647. https://doi.org/10.1016/j.tet.2019.07.009

4.) Momenteau, et al. Both-faces Hindered Porphyrins. Part 1. Synthesis and Characterization of Basket-handle Porphyrins and Their Iron Complexes. Journal of the Chemical Society. Perkin transactions I, 1983, # 1, p. 189 – 196. https://doi.org/10.1039/P19830000189

5.) Sugiyasu, et al. Conducting polymer networks cross-linked by “isolated” functional dyes: Design, synthesis, and electrochemical polymerization of doubly strapped light-harvesting porphyrin/oligothiophene monomers. Chemistry – A European Journal, 2009, vol. 15, # 26, p. 6350 – 6362. https://doi.org/10.1002/chem.200900576

6.) Staeubli, et al. Synthetic Models of the Active Site of Cytochrome P-450. 1st Communication. The Synthesis of a Doubly-Briged Iron(II)-Porphyrin Carrying a Tightly Bound Thiolate Ligand. Helvetica Chimica Acta, 1987, vol. 70, p. 1173 – 1193. https://doi.org/10.1002/hlca.19870700425
Categories

Functional Groups

, ,

Porphyrin Family

A4 Porphyrins, Free Base Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

Purity %

>95%

Molecular Formula

C48H38N4O4

Molecular Weight

734.84

CAS #

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