Fe(III) meso-Tetra(4-carboxyphenyl)porphine chloride

Fe(III) meso-Tetra(4-carboxyphenyl)porphine chloride meso-Tetraphenylporphine- 4,4′,4”,4”’-tetracarboxylic acid, iron (III) chloride CAS: 55266-17-6 MDL: MFCD03425968

SDS

Molecular weight: 880.06 g/mol

Molecular Formula: C₄₈H₂₈ClFeN₄O₈

CAS Number:  55266-17-6

Storage: Store at room temperature, protect from light

Purity: >95%

Synonyms:  5,10,15,20-TETRAKIS-(4-CARBOXYPHENYL)-PORPHYRIN-FE-(III) CHLORIDE, MESO-TETRAPHENYLPORPHINE-4,4′,4”,4”’-TETRACARBOXYLIC ACID, IRON (III) CHLORIDE,  FE(III) MESO-TETRA(4-CARBOXYPHENYL)PORPHINE CHLORIDE 

Background: Fe(III) meso-Tetra(4-carboxyphenyl)porphine chloride is a porphyrin derivative manufactured by Frontier Specialty Chemicals. Fe(III) meso-Tetra(4-carboxyphenyl)porphine chloride generates ROS as evidenced by ESR spectra, and is a biomimetic of cytochromes and Heme. ^1,2   It is used in MOFs to react with organic molecules for nanofiltration,  and in oxidation of biomolecules such as lignin and organic heterocycles ^3,4

References:

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1.)  Kim, Yoon-Soo; Lee, Young-Chul; Lee, Hyun Uk; Huh, Yun Suk; Shin, Hyun-Jae, Visible-light-responsive porphyrin-incorporated TiO2 treatment of diatom matrix, Journal of Nanoscience and Nanotechnology (2016), 16(9), 9699-9707. DOI:10.1166/jnn.2016.12038.

2.)  Kohn, Tamar; Arnold, William A.; Roberts, A. Lynn, Reactivity of Substituted Benzotrichlorides toward Granular Iron, Cr(II), and an (II) Porphyrin: A Correlation Analysis, Environmental Science & Technology (2006), 40(13), 4253-4260. DOI:10.1021/es051737x.

3.)  Sharits, Andrew; Placido, Andrew; Morton, Samuel A., III; Morton, Laurel A., Oxidation of lignin model compounds using Fe(III)meso-tetra(4-sulfonatophenyl)porphine chloride and Fe(III)meso-tetra(4-carboxyphenyl)porphine, Abstracts of Papers, 241st ACS National Meeting & Exposition, Anaheim, CA, United States, March 27-31, 2011 (2011), INOR-298.

4.)  Yu, Zongjiang; Zhai, Guoqing; Xian, Mo; Lu, Ming; Wang, Pengcheng; Jiang, Tao; Xu, Chao; Sun, Weizhi, Biomimetic Cleavage of Aryl-Nitrogen Bonds in N-Arylazoles Catalyzed by Metalloporphyrins, Catalysis Letters (2018), 148(9), 2636-2642., DOI:10.1007/s10562-018-2446-9