Fe(III) meso-Tetra (4-pyridyl) Porphine Chloride

Catalog#: T10392; CAS Number: 55621-88-0

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Fe(III) meso-Tetra (4-pyridyl) Porphine Chloride CAS: 55621-88-0 MDL: MFCD31567403

Molecular weight: 707.97 g/mol

Molecular Formula: C40H24ClFeN8

CAS Number: 55621-88-0

Storage: Store at room temperature, protect from light.

Synonyms: Fe(III) meso-Tetra (4-pyridyl) Porphine Chloride, 55621-88-0, MFCD31567403, FeTPyP

Fields of Interest: Synthetic Porphyrins, Iron (III) Porphyrins, Catalysis, Oxygen Electroreduction

Background: Fe(III) meso-Tetra (4-pyridyl) Porphine Chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Fe(III) meso-Tetra (4-pyridyl) Porphine Chloride  acts as an electrocatalyst for selective oxygen reduction to water.1-2

References: 

1.) Kong, et al. Hierarchically porous few-layer porphyrinic carbon nanosheets formed by a VOx-templating method for high-efficiency oxygen electroreduction. J. Mater. Chem. A, 2016,4, 7305-7312. https://doi.org/10.1039/C6TA00154H

2.) Matson, et al. Distant protonated pyridine groups in water-soluble iron porphyrin electrocatalysts promote selective oxygen reduction to water. Chem. Commun., 2012,48, 11100-11102. https://doi.org/10.1039/C2CC35576K

3.) Zakavi, et al. Stereoelectronic effects of the meso-substituents on the catalytic performance of iron(III) meso-tetraarylporphyrins: Pyridyl and N-methylated pyridyl groups compared to phenyl, 4-methoxyphenyl and 4-sulfonatophenyl ones. Journal of Molecular Catalysis A: Chemical. Volume 367, February 2013, Pages 108-115. https://doi.org/10.1016/j.molcata.2012.11.003

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[55621-88-0]

Purity %

>95%

Smiles

Cl[Fe]1N2C3=CC=C2C(C2=CC=NC=C2)=C2C=CC(=N2)/C(C2=CC=NC=C2)=C2/C=CC(N12)=C(C1=NC(C=C1)=C/3C1=CC=NC=C1)C1=CC=NC=C1

Molecular Weight

707.97

Molecular Formula

C40H24ClFeN8

Functional Groups

Nitrogen Heterocycle

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins, Pyridyl Substituted Porphyrins

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