Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride

Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride CAS: 87261-83-4 MDL: MFCD18070955

Molecular weight: 806.29 g/mol

Molecular Formula:  C₄₀H₂₄Cl₂N₈Sn

CAS Number: 87261-83-4

Storage: Store at room temperature, protect from light

Synonyms:  (1Z,6Z,12Z,17Z)-22,22-Dichlor-2,7,12,17-tetra(4-pyridinyl)-21,23,24,25-tetraaza-22-stannahexacyclo[9.9.3.1^3,6.1^13,16.0^8,23.0^18,21]pentacosa-1,3(25),4,6,8,10,12,14,16(24),17,19-undecaen, (1Z,6Z,12Z,17Z)-22,22-Dichloro-2,7,12,17-tetra(4-pyridinyl)-21,23,24,25-tetraaza-22-stannahexacyclo[9.9.3.1^3,6.1^13,16.0^8,23.0^18,21]pentacosa-1,3(25),4,6,8,10,12,14,16(24),17,19-undecaene, (1Z,6Z,12Z,17Z)-22,22-Dichloro-2,7,12,17-tétra(4-pyridinyl)-21,23,24,25-tétraaza-22-stannahexacyclo[9.9.3.1^3,6.1^13,16.0^8,23.0^18,21]pentacosa-1,3(25),4,6,8,10,12,14,16(24),17,19-undécaène, 87261-83-4, MFCD18070955, Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride, dichloro-(5,10,15,20-tetrakis-(4-pyridyl)-porphyrinato)tin(IV)

Field of Interest: Catalysis, Electrocatalysis, Surfaces, Self-Assembly, Solar Cells

Background: Sn(IV) meso-Tetra (4-Pyridyl) Porphine Dichloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

1.) Koposova, et al. Influence of Meso-Substitution of the Porphyrin Ring on Enhanced Hydrogen Evolution in a Photochemical System. J. Phys. Chem. C 2016, 120, 26, 13873–13890. https://doi.org/10.1021/acs.jpcc.6b01467

2.) Ajayi, et al. Photocurrent and photoelectrochemical hydrogen production with tin porphyrin and platinum nanowires immobilized with nafion on glassy carbon electrode. International Journal of Hydrogen Energy. Volume 34, Issue 1, January 2009, Pages 110-114. https://doi.org/10.1016/j.ijhydene.2008.09.092

3.) Oppelt, et al. Photocatalytic reduction of artificial and natural nucleotide co-factors with a chlorophyll-like tin-dihydroporphyrin sensitizer. Inorganic Chemistry, 2013, vol. 52, # 20, p. 11910 – 11922. https://doi.org/10.1021/ic401611v

4.) Wang, et al. Porphyrin nanotubes by ionic self-assembly. Journal of the American Chemical Society, 2004, vol. 126, # 49, p. 15954 – 15955. https://doi.org/10.1021/ja045068j

5.) Mongwaketsi, Synthesis and characterization of porphyrin nanotubes/rods for solar radiation harvesting and solar cells. Physica B: Condensed Matter, 2012, vol. 407, # 10, p. 1615 – 1619. https://doi.org/10.1016/j.physb.2011.09.099

6.) Shee, et al. Hexacoordinated Sn(IV) porphyrin-based square-grid frameworks exhibiting selective uptake of CO₂ over N₂. Bulletin of the Korean Chemical Society, 2022, vol. 43, # 1, p. 103 – 109.