Vanadyl meso-tetraphenylporphine (1-3% chlorin)

Vanadyl meso-tetraphenylporphine (1-3% chlorin) 5,10,15,20-Tetraphenyl-21H,23H-porphine vanadium(IV) oxide CAS: 14705-63-6 MDL: MFCD00012154

SDS

Molecular weight: 679.661 g/mol

Molecular Formula: C₄₄H₂₈N₄OV

CAS Number: 14705-63-6

Storage: Store at room temperature, protect from light

Synonyms: 14705-63-6, MFCD00012154, Oxo[5,10,15,20-tetraphenylporphinato(2-)]vanadium, Oxo[5,10,15,20-tetraphenylporphyrinato(2-)-κ²N²¹,N²³]vanadium, Oxo[5,10,15,20-tetraphenylporphyrinato(2-)-κ²N²¹,N²³]vanadium, Oxo[5,10,15,20-tétraphénylporphyrineato(2-)-κ²N²¹,N²³]vanadium, Vanadium, oxo[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN²¹,κN²³], Vanadyl(IV) meso-tetraphenylporphine, 5,10,15,20-Tetraphenyl-21H,23H-porphine vanadium(IV) oxide, 5,10,15,20-Tetraphenyl-21h,23h-porphinevanadium(iv)oxide, vanadyl mesotetraphenylporphine, Vanadyl meso-tetraphenylporphine

Field of Interest: Model compounds for vanadium containing crude oils, Epoxidation, Catalysis

Background: Vanadyl meso-tetraphenylporphine (1-3% chlorin) is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Vanadyl meso-tetraphenylporphine has been used as a model for vanadium compounds in crude oil.¹ Vanadyl meso-tetraphenylporphine is a selective catalyst for the epoxidation of olefins.²

References: 

1.) Dechaine, et al. Chemistry and Association of Vanadium Compounds in Heavy Oil and Bitumen, and Implications for Their Selective Removal. Energy Fuels 2010, 24, 5, 2795–2808. https://doi.org/10.1021/ef100173j

2.) Maurya, et al. Selective epoxidation of olefins by vanadylporphyrin [VO(TPP)] and electron deficient nonplanar B-octabromovanadylporphyrin [VO(TPPBr₈)]. Journal of Porphyrins and PhthalocyaninesVol. 26, No. 03, pp. 187-194 (2022).

3.) Taghavi, et al. Investigation of catalytic activity of high-valent vanadium(IV) tetraphenylporphyrin: A new, highly efficient and reusable catalyst for acetylation of alcohols and phenols with acetic anhydride. Inorganica Chimica Acta, 2011, vol. 377, # 1, p. 159 – 164. https://doi.org/10.1016/j.ica.2011.07.036

4.) Bai, et al. Cycloaddition of epoxide and CO₂ to cyclic carbonate catalyzed by VO(IV) porphyrin. Applied Organometallic Chemistry, 2015, vol. 29, # 4, p. 240 – 243. https://doi.org/10.1002/aoc.3278