Cr(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin)

Product Number: T41015; CAS Number: 28110-70-5

T41015 Technical Data Sheet

SDS

$166.00$436.00

$166.00
$436.00

Cr(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin) CAS: 28110-70-5 MDL: MFCD0026981

SDS

Molecular weight: 700.18  g/mol

Molecular Formula: C44H28ClCrN4

CAS Number: 28110-70-5

Storage: Store at room temperature, protect from light.

Purity: >95%

Synonyms:   Salicylate Ionophore I, meso-Tetraphenylporphyrine Chromium(III) chloride. Chromiumtetraphenylporphinechloride, Meso-Tetraphenylporphyrin-Cr(III) chloride, Chromium(III) Tetraphenylporphine Chloride, Chloro(meso- tetraphenylporphinato)chromium, Chromium (III) Tetraphenylporphine Chloride, 5,10,15,20-Tetraphenylporphyrin Cr(III) Chloride, 5,10,15,20-Tetraphenyl-21H,23H- porphine chromium(III), Chromium(III) 5,10,15,20-tetraphenylporphine chloride, 21H,23H-Porphine, 5,10,15,20-tetraphenyl-, chromium(3+) salt, hydrochloride (1:1:1), Chlorure 5,10,15,20-tétraphénylporphine-21,23-diide de chrome(3+) (1:1:1), Chrom(3+)chlorid-5,10,15,20-tetraphenylporphin-21,23-diid (1:1:1), Chromium(3+) chloride 5,10,15,20-tetraphenylporphine-21,23-diide (1:1:1), 28110-70-5, CHROMIUM (III) TETRAPHENYLPORPHINE CHLORIDE, Chromium(III) tetraphenylporphine chloride, MFCD00269817

Field of Interest: Catalysis, epoxide carbonylation, sensors, ion selective electrodes, Epoxidation

Background: Cr(III) meso-Tetraphenylporphine Chloride (contains 1-3% chlorin) is a synthetically derived metallophorphyrin specialty chemical manufactured by Frontier Specialty Chemicals containing chromium in the (III) oxidation state. This complex has been used for the construction of an salicylate-selective membrane electrode.1 Cr(III) meso-Tetraphenylporphine Chloride in combination with dicobalt octacarbonyl produces a highly active catalytic species for the carbonylation of epoxides to B-lactones, avoiding the need to handle air sensitive intermediates for the preparation of the Coates catalyst.2 Cr(III) meso-Tetraphenylporphine Chloride was used to polymerize styrene oxide catalytically under various conditions in the presence of bis(triphenylphosphine)iminium chloride.3 Exo-selective epoxidation of norbornene  was accomplished using Cr(III) meso-Tetraphenylporphine Chloride as a catalyst.4 Cr(III) meso-Tetraphenylporphine Chloride catalyzed the  dehydrogenative synthesis of imines from alcohols and amines.5 Cr(III) meso-Tetraphenylporphine Chloride was used to synthesize a selectively functionalized polylactide polymer.6

References:

1.) Shahrokhian, S., Hamzehloei, A., Bagherzadeh, M.; Chromium(III) Porphyrin as a selective ionophore in a salicylate-selective membrane electrode. Anal Chem. 2002,14, 3312-3320. doi: 10.1021/ac020099n.

2.) Ganji, P., Doyle, D.J., Ibrahim, H.; In Situ Generation of the Coates Catalyst: A Practical and Versatile Catalytic System for the Carbonylation of meso-Epoxides. Lett. 2011, 12, 3142-3145. https://doi.org/10.1021/ol201043d

3.) Harrold, et al. Studies of Ring-Opening Reactions of Styrene Oxide by Chromium Tetraphenylporphyrin Initiators. Mechanistic and Stereochemical Considerations. Macromolecules 2013, 46, 3, 692–698. https://doi.org/10.1021/ma302492p

4.) Traylor, et al. Alkene epoxidations catalyzed by iron(III), manganese(III), and chromium(III) porphyrins. Effects of metal and porphyrin substituents on selectivity and regiochemistry of epoxidation. J. Am. Chem. Soc. 1989, 111, 19, 7443–7448. https://doi.org/10.1021/ja00201a026

5.) Miao, et al. Vanadium- and Chromium-Catalyzed Dehydrogenative Synthesis of Imines from Alcohols and Amines. Organometallics 2021, 40, 9, 1328–1335. https://doi.org/10.1021/acs.organomet.1c00123

6.) Balasanthiran, et al. Coupling of Propylene Oxide and Lactide at a Porphyrin Chromium(III) Center. J. Am. Chem. Soc. 2015, 137, 5, 1786–1789. https://doi.org/10.1021/ja512554t

 

Categories

Metal

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

Purity %

>95%

Molecular Formula

C44H28ClCrN4

Molecular Weight

700.169

CAS #

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