Mn (III) Octaethylporphine chloride CAS: 28265-17-0 MDL: MFCD00074839
Molecular weight: 623.15Â g/mol
Molecular Formula: C36H44ClMnN4
CAS Number: 28265-17-0
Storage: Store at room temperature, protect from light.
Synonyms: Chlor[2,3,7,8,12,13
Fields of Interest: Synthetic Porphyrins, Catalysis
Background: Mn (III) Octaethylporphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.
References:
1.) Golubkov, et al. Nitrogen atom transfer between manganese complexes of salen, porphyrin, and corrole and characterization of a (nitrido)manganese(VI) corrole. Journal of the American Chemical Society, 2005, vol. 127, # 10, p. 3258 – 3259. https://doi.org/10.1021/ja043683h
2.) Cheng, et al. A Novel Dimanganese(III) Complex with a Single Hydroxo Bridge. Syntheses, Structures, and Magnetic Susceptibilities of (μ-Hydroxo)bis((octaethylporphinato)manganese(III)) Perchlorate and a Monomeric Precursor, Aquo(octaethylporphinato)manganese(III) Perchlorate. Inorganic Chemistry, 1995, vol. 34, p. 4627 – 4639. https://doi.org/10.1021/ic00122a020
3.) Dmitrieva, et al. Meso-nitro substitution as a means of Mn-octaethylporphyrin redox state controlling. Journal of Organometallic Chemistry, 2021, vol. 940, art. no. 121790. https://doi.org/10.1016/j.jorganchem.2021.121790
4.) Bottomley, et al. Stereoelectronic Aspects of Inter-Metal Nitrogen Atom Transfer Reactions between Nitridomanganese(V) and Chromium(III) Porphyrins. Inorganic Chemistry, 1997, vol. 36, # 24, p. 5435 – 5439. https://doi.org/10.1021/ic960919c
