Rh(III) Octaethylporphine chloride CAS: 36670-30-1 MDL: MFCD32267980
Molecular weight: 671.12 g/mol
Molecular Formula:Â C36H44ClN4Rh
CAS Number: 36670-30-1
Storage:Â Store at room temperature, protect from light
Synonyms: Rh(III) Octaethylporphine chloride, 36670-30-1, MFCD32267980
Field of Interest: Catalysis, Electrocatalysis
Background: Rh(III) Octaethylporphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.
References:Â
1.) Wayland, et al. Dioxygen and nitric oxide complexes of rhodium porphyrins. Inorg. Chem. 1981, 20, 9, 3093–3097. https://doi.org/10.1021/ic50223a067
2.) Yamazaki, et al. Characterization of a Rh(iii) porphyrin–CO complex: its structure and reactivity with an electron acceptor. Dalton Trans., 2015,44, 13823-13827. https://doi.org/10.1039/C5DT01453K
3.) Yamazaki, et al. Electrochemical oxidation of oxalic acid by Rh octaethylporphyrin adsorbed on carbon black at low overpotential. Journal of Electroanalytical Chemistry. Volume 602, Issue 1, 1 April 2007, Pages 96-102. https://doi.org/10.1016/j.jelechem.2006.12.010
4.) Yamazaki, et al. Efficient Electrochemical Conversion of Carbon Monoxide by Rhodium Octaethylporphyrin Adsorbed on Carbon Black. Inorg. Chem. 2005, 44, 19, 6512–6514. https://doi.org/10.1021/ic050911f