Rh(III) Octaethylporphine chloride

Product Number: O40151; CAS Number: 36670-30-1

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Rh(III) Octaethylporphine chloride CAS: 36670-30-1 MDL: MFCD32267980

Molecular weight: 671.12 g/mol

Molecular Formula: C36H44ClN4Rh

CAS Number: 36670-30-1

Storage: Store at room temperature, protect from light

Synonyms: Rh(III) Octaethylporphine chloride, 36670-30-1, MFCD32267980

Field of Interest: Catalysis, Electrocatalysis

Background: Rh(III) Octaethylporphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

1.) Wayland, et al. Dioxygen and nitric oxide complexes of rhodium porphyrins. Inorg. Chem. 1981, 20, 9, 3093–3097. https://doi.org/10.1021/ic50223a067

2.) Yamazaki, et al. Characterization of a Rh(iii) porphyrin–CO complex: its structure and reactivity with an electron acceptor. Dalton Trans., 2015,44, 13823-13827. https://doi.org/10.1039/C5DT01453K

3.) Yamazaki, et al. Electrochemical oxidation of oxalic acid by Rh octaethylporphyrin adsorbed on carbon black at low overpotential. Journal of Electroanalytical Chemistry. Volume 602, Issue 1, 1 April 2007, Pages 96-102. https://doi.org/10.1016/j.jelechem.2006.12.010

4.) Yamazaki, et al. Efficient Electrochemical Conversion of Carbon Monoxide by Rhodium Octaethylporphyrin Adsorbed on Carbon Black. Inorg. Chem. 2005, 44, 19, 6512–6514. https://doi.org/10.1021/ic050911f

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[36670-30-1]

Purity %

>95%

Smiles

CCC1=C(CC)C2=NC1=C/C1=C(CC)C(CC)=C3N1[Rh](Cl)N1C(=C2)/C(CC)=C(CC)C1=CC1=NC(=C/3)C(CC)=C1CC

Molecular Weight

671.12

Molecular Formula

C36H44ClN4Rh

Functional Groups

Alkyl

Porphyrin Family

Metallo Porphyrins, Octaethyl Porphyrins

Porphyrin Substitution

Alkyl Substituted Porphyrins, Beta Substituted Porphyrins

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