meso-Tetra(4-N,N-dimethylanilinium) porphine

meso-Tetra(4-N,N-dimethylanilinium) porphine CAS: 14945-24-5 MDL: MFCD01074432

Molecular weight: 787.01 g/mol

Molecular Formula: C₅₂H₅₀N₈

CAS Number: 14945-24-5

Storage: Store at room temperature, protect from light.

Synonyms: 4,4′,4”,4”’-(5,10,15,20-Porphyrinetétrayl)tétrakis(N,N-diméthylaniline), 4,4′,4”,4”’-(5,10,15,20-Porphyrintetrayl)tetrakis(N,N-dimethylanilin), 4,4′,4”,4”’-(5,10,15,20-Porphyrintetrayl)tetrakis(N,N-dimethylaniline), Benzenamine, 4,4′,4”,4”’-(21H,23H-porphine-5,10,15,20-tetrayl)tetrakis[N,N-dimethyl-, Dimethyl(4-{7,12,17-tris[4-(dimethylamino)phenyl]-21,22,23,24-tetraazapentacyclo[16.2.1.1<3,6>.1<8,11>.1<13,16>]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaen-2-yl}phenyl)amine, 5,10,15,20-TETRA(4-DIMETHYLAMINOPHENYL)PORPHYRIN, 5,10,15,20-tetrakis(4-(N,N-dimethylamino)phenyl)-21H,23H-porphine, 5,10,15,20-Tetrakis(4-dimethylaminophenyl)porphyrin

Fields of Interest: Synthetic Porphyrins

Background: meso-Tetra(4-N,N-dimethylanilinium) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Ojadi, et al. Sequential Protonation of meso-(p-(Dimethylamino)phenyl)porphyrins: Charge-Transfer Excited States Producing Hyperporphyrins. Journal of Physical Chemistry, 1993, vol. 97, # 50, p. 13192 – 13197. https://doi.org/10.1021/j100152a025

2.) Kojima, et al. Metal-free C(3)-H arylation of coumarins promoted by catalytic amounts of 5,10,15,20-tetrakis(4-diethylaminophenyl)porphyrin. Chemical Communications, 2015, vol. 51, # 47, p. 9718 – 9721. https://doi.org/10.1039/C5CC02349A

3.) Weinkauf, et al. Substituent and solvent effects on the hyperporphyrin spectra of diprotonated tetraphenylporphyrins. Journal of Physical Chemistry A, 2003, vol. 107, # 18, p. 3486 – 3496. https://doi.org/10.1021/jp022046f