meso-Tetra (4-chlorophenyl) porphine

Product Number: T40516; CAS Number: 22112-77-2

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meso-Tetra (4-chlorophenyl) porphine 5,10,15,20-Tetrakis(4-chlorophenyl)-21H,23H-porphine CAS: 22112-77-2 MDL: MFCD00830318

Molecular weight: 752.52 g/mol

Molecular Formula: C44H26Cl4N4

CAS Number: 22112-77-2

Storage: Store at room temperature, protect from light.

Synonyms: 2,7,12,17-tetra(4-chlorophenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.13,6.18,11.113,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 21H,23H-Porphine, 5,10,15,20-tetrakis(4-chlorophenyl)-, 22112-77-2, 5,10,15,20-Tetrakis(4-chlorophenyl)porphyrin, 5,10,15,20-Tétrakis(4-chlorophényl)porphyrine, 5,10,15,20-Tetrakis(4-chlorphenyl)porphyrin, Tetra(p-chlorophenyl)porphine, Tetra-p-chlorophenylporphyrin, 2,7,12,17-tetrakis(4-chlorophenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1³,?.1?,¹¹.1¹³,¹?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 5,10,15,20-Tetrakis(4-chlorophenyl)-21H,23H-porphine, 5,10,15,20-Tetrakis(4-chlorophenyl)porphine, 5,10,15,20-tetrakis(p-chlorophenyl) porphyrin, meso-Tetra (4-chlorophenyl) porphine, meso-tetrakis-(4-chlorophenyl)porphyrin, MFCD00830318, tetra-(4-chlorophenyl)-porphyrin

Fields of Interest: Synthetic Porphyrins, Halogenated Porphyrins

Background: meso-Tetra (4-chlorophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Wang, et al. Controlling the Nature of Mixed (Phthalocyaninato)(porphyrinato) Rare-Earth(III) Double-Decker Complexes: The Effects of Nonperipheral Alkoxy Substitution of the Phthalocyanine Ligand. Chemistry, A European Journal. Volume 12, Issue 5, February 1, 2006, Pages 1475-1485. https://doi.org/10.1002/chem.200500733

2.) Kan, et al. Sandwich-Type Mixed Tetrapyrrole Rare-Earth Triple-Decker Compounds. Effect of the Coordination Geometry on the Single-Molecule-Magnet Nature. Inorg. Chem. 2013, 52, 15, 8505–8510. https://doi.org/10.1021/ic400485y

3.) Belcher, et al. Porphyrin complexes containing coordinated BOB groups: synthesis, chemical reactivity and the structure of [BOB(tpClpp)]2+. Dalton Trans., 2008, 1602-1614. https://doi.org/10.1039/B716189A

4.) Zhu, et al. Effect of substituent groups of porphyrins on the electroluminescent properties of porphyrin-doped OLED devices. Journal of Physical Organic Chemistry. Volume 23, Issue 3, March 2010, Pages 190-194.

5.) Guergueb, et al. Effect of the coordination of π-acceptor 4-cyanopyridine ligand on the structural and electronic properties of meso-tetra(para-methoxy) and meso-tetra(para-chlorophenyl) porphyrin cobalt(ii) coordination compounds. Application in the catalytic degradation of methylene blue dye. RSC Adv., 2020,10, 6900-6918. https://doi.org/10.1039/C9RA08504A

 

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[22112-77-2]

Purity %

>95%

Smiles

ClC1=CC=C(C=C1)C1=C2NC(C=C/2)=C(/C2=N/C(/C=C2)=C(C2=CC=C(N2)/C(=C2/C=CC1=N/2)C1=CC=C(Cl)C=C1)C1=CC=C(Cl)C=C1)C1=CC=C(Cl)C=C1

Molecular Weight

752.52

Molecular Formula

C44H26Cl4N4

Functional Groups

Chloro, Halogenated

Porphyrin Family

A4 Porphyrins, Free Base Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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