meso-Tetra (p-bromophenyl) porphine

Product Number: T40533; CAS Number: 29162-73-0



meso-Tetra (p-bromophenyl) porphine 5,10,15,20-Tetrakis(4-bromophenyl)-21H,23H-porphine CAS: 29162-73-0 MDL: MFCD02114459

Molecular weight: 930.32 g/mol

Molecular Formula: C44H26Br4N4

CAS Number: 29162-73-0

Storage: Store at room temperature, protect from light

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(4-bromophenyl)-, 5,10,15,20-Tetrakis(4′-bromophenyl)porphyrin, 5,10,15,20-Tetrakis(4-bromophenyl)porphyrin, 5,10,15,20-Tétrakis(4-bromophényl)porphyrine, 5,10,15,20-Tetrakis(4-bromphenyl)porphyrin, MFCD02114459, 2,7,12,17-TETRAKIS(4-BROMOPHENYL)-21,22,23,24-TETRAAZAPENTACYCLO[,6).1(8,11).1(13,16)]TETRACOSA-1,3,5,7,9,11(23),12,14,16,18(21),19-UNDECAENE, 29162-73-0, 5,10,15,20-tetrakis(4-bromophenyl)-21,22-dihydroporphyrin, 5,10,15,20-Tetrakis(4-bromophenyl)-21H,23H-porphine, 5,10,15,20-四(4-溴基苯基)卟啉, meso-Tetra (p-bromophenyl) porphine

Field of Interest: Synthetic Porphyrins, Suzuki Coupling, Covalent Organic Frameworks COFs

Background: meso-Tetra (p-bromophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.


1.) Chen, et al. CMPs as Scaffolds for Constructing Porous Catalytic Frameworks: A Built-in Heterogeneous Catalyst with High Activity and Selectivity Based on Nanoporous Metalloporphyrin Polymers.  J. Am. Chem. Soc. 2010, 132, 26, 9138–9143.

2.) Lv, et al. A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation. J. Am. Chem. Soc. 2017, 139, 1, 211–217.

3.) Liang, et al. Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide. Chem. Soc. Rev., 2021,50, 2540-2581. DOI

4.) Wang, et al. A porous covalent porphyrin framework with exceptional uptake capacity of saturated hydrocarbons for oil spill cleanup. Chem. Commun., 2013,49, 1533-1535.

5.) Yuan, et al. Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal–Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers. Angewandte Chemie – International Edition, 2018, vol. 57, # 20, p. 5708 – 5713.

6.) Biswal, et al. Nonlinear Optical Switching in Regioregular Porphyrin Covalent Organic Frameworks. Angewandte Chemie – International Edition, 2019, vol. 58, # 21, p. 6896 – 6900.

7.) Lu, et al. Synthesis of a conjugated porous Co(ii) porphyrinylene–ethynylene framework through alkyne metathesis and its catalytic activity study. J. Mater. Chem. A, 2015,3, 4954-4959.

8.) Liu, et al. Synthesis and photovoltaic properties of polythiophene stars with porphyrin core. Journal of Materials Chemistry, 2010, vol. 20, # 6, p. 1140 – 1146.

9.) Gao, et al. General and Efficient Synthesis of Arylamino- and Alkylamino-Substituted Diphenylporphyrins and Tetraphenylporphyrins via Palladium-Catalyzed Multiple Amination Reactions. J. Org. Chem. 2003, 68, 16, 6215–6221.

10.) Eder, et al. A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO2 to formateChemical Communications, 2019, vol. 55, # 50, p. 7195 – 7198.



Functional Groups


Porphyrin Family

A4 Porphyrins, Free Base Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

Purity %


Molecular Formula


Molecular Weight



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