Porphyrins

Water-Soluble Nitroxyl Porphyrin Complexes FeIITPPSHNO and FeIITPPSNO− Obtained from Isolated FeIITPPSNO•

Recent work from the Doctorovich group at the University of Buenos Aires published in JACS identified the first biomimetic water-soluble FeII-porphyrin nitroxyl complexes. A pKa was calculated for the complex and reaction kinetics measured. DFT calculations implied the formation of a phlorin radical intermediate for the investigated reaction. Thanks for using our meso-tetra(4-sulfonatophenyl)porphine, T40699. 

Water-Soluble Nitroxyl Porphyrin Complexes FeIITPPSHNO and FeIITPPSNO− Obtained from Isolated FeIITPPSNO• Read More »

Dioxygen at Biomimetic Single Metal‑Atom Sites: Stabilization or Activation? The Case of CoTPyP/Au(111)

Recent work from the Vesselli group at the University of Trieste published in Topics in Catalysis demonstrated both experimental and computational results for the metal-organic framework (MOF) structure of 5,10,15,20-tetra(4-pyridyl)21H,23H-porphyrin cobalt(III) chloride assembled on a Au(111) surface. The generated MOF was able to mimic O2 stabilization and activation mechanisms typically observed in proteins and enzymes. Thanks for using our cobalt tetrapyridylporphyrin, T40892. 

Dioxygen at Biomimetic Single Metal‑Atom Sites: Stabilization or Activation? The Case of CoTPyP/Au(111) Read More »

Porphyrin loaded TyroSpheres for the intracellular delivery of drugs and photo-induced oxidant species.

Cat. No: D40922 Cat. No: T40637 TyroSphere nanoparticles consisting of the triblock polymer [poly(ethyleneglycol)-block-oligio(desaminotyrosine octyl ester suberate)-block -poly(ethyleneglycol)] aggregates were loaded with amphiphilic porphyrins as reported by Tsubone, et al. Meso-cis-di(N-methyl-4-pyridyl)diphenylporphine dichloride Cat. No: D40922 , which is a positively charged porphyrin and meso-cis-di(4-sulfonatophenyl)-diphenylporphine dihydrochloride Cat. No: T40637, a negatively charged porphyrin were used. The

Porphyrin loaded TyroSpheres for the intracellular delivery of drugs and photo-induced oxidant species. Read More »

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