Zn(II) Octaethylporphine

Zn(II) Octaethylporphine CAS: 17632-18-7 MDL: MFCD00012156

Molecular weight: 598.17 g/mol

Molecular Formula: C₃₆H₄₄N₄Zn

CAS Number: 17632-18-7

Storage: Store at room temperature, protect from light

Synonyms: [2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ²N²¹,N²³]zinc, [2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ²N²¹,N²³]zink,[2,3,7,8,12,13,17,18-Octaéthylporphyrineato(2-)-κ²N²¹,N²³]zinc, 17632-18-7, MFCD00012156, Zinc, [2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-κN²¹,κN²³]-,[2,3,7,8,12,13,17,18-octaethylporphyrinato(2-)-κ(4)N(21),N(22),N(23),N(24)]zinc, 2 3 7 8 12 13 17 18-OCTAETHYL-21H 23H-2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphine zinc(II), 237812131718-OCTAETHYL-21H23H-zinc octaethylporphyrin, Zinc,[2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-kN21,kN22,kN23,kN24]-, (SP-4-1)-, Zn(II) Octaethylporphine

Field of Interest: Zinc Porphyrins

Background: Zn(II) Octaethylporphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

1.) Yoshimoto, et al. Controlled molecular orientation in an adlayer of a supramolecular assembly consisting of an open-cage C₆₀ derivative and Zn^II octaethylporphyrin on Au(111). Angewandte Chemie – International Edition, 2004, vol. 43, # 23, p. 3044 – 3047. https://doi.org/10.1002/anie.200453959

2.) Schweitzer, et al. Mechanism of photosensitized generation of singlet oxygen during oxygen quenching of triplet states and the general dependence of the rate constants and efficiencies. Journal of Physical Chemistry A, 2003, vol. 107, # 13, p. 2192 – 2198. https://doi.org/10.1021/jp026189d

3.) Liu, et al. Photophysics of soret-excited tetrapyrroles in solution. II. Effects of perdeuteration, substituent nature and position, and macrocycle structure and conformation in zinc(II) porphyrins. Journal of Physical Chemistry A, 2008, vol. 112, # 38, p. 8986 – 8998. https://doi.org/10.1021/jp804792x

4.) Amashukeli, et al. Inner-sphere electron-transfer reorganization energies of zinc porphyrins. Journal of the American Chemical Society, 2004, vol. 126, # 47, p. 15566 – 15571. https://doi.org/10.1021/ja0351037

5.) Ji, et al. ZnOEP based phototransistor: Signal amplification and light-controlled switch. Chemical Communications, 2008, # 23, p. 2653 – 2655. https://doi.org/10.1039/B805204B

6.) Yoshimoto, et al. Supramolecular assembly of [60] fullerene and highly ordered zinc octaethylporphyrin adlayer formed on Au(111) surface. Chemistry Letters, 2004, vol. 33, # 7, p. 914 – 915. https://doi.org/10.1246/cl.2004.914