Mn(III) meso-Tetraphenylporphine acetate (1-3% chlorin)

Product Number: T40734; CAS Number: 58356-65-3

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Mn(III) meso-Tetraphenylporphine acetate (1-3% chlorin) CAS: 58356-65-3 MDL: MFCD00216548

Molecular weight: 726.70 g/mol

Molecular Formula: C46H31MnN4O2

CAS Number: 58356-65-3

Storage: Store at room temperature, protect from light.

Synonyms: Mn(III) meso-Tetraphenylporphine acetate, Acétate 5,10,15,20-tétraphénylporphine-21,23-diide de manganèse(3+) (1:1:1), Mangan(3+)acetat-5,10,15,20-tetraphenylporphin-21,23-diid (1:1:1), 58356-65-3,Acetato(meso-tetraphenylporphyrinato)manganese(III), MFCD00216548

Fields of Interest: Synthetic Porphyrins, Catalysis,

Background: Mn(III) meso-Tetraphenylporphine acetate (1-3% chlorin) is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Suslik, et al. Regioselective Epoxidations of Dienes with Manganese(III) Porphyrin Catalysts. Journal of the Chemical Society. Chemical communications, 1987, # 3, p. 200 – 202. https://doi.org/10.1039/C39870000200

2.) Haber, et al. Manganese porphyrins as catalysts for oxidation of cyclooctane in Lyons system. Journal of Molecular Catalysis A: Chemical, 2000, vol. 162, # 1-2, p. 105 – 109. https://doi.org/10.1016/S1381-1169(00)00324-1

3.) Mojarrad, et al. Short time biomimetic oxidation of styrene with aqueous hydrogen peroxide: Crucial roles played by acetic acid. Polyhedron, 2021, vol. 207. https://doi.org/10.1016/j.poly.2021.115377

4.) Rezaeifard, et al. Nanoaggregates of simple Mn porphyrin complexes as catalysts for the selective oxidation of hydrocarbons. European Journal of Inorganic Chemistry, 2013, # 14, p. 2657 – 2664. https://doi.org/10.1002/ejic.201201437

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[58356-65-3]

Purity %

>95%

Smiles

CC(=O)O[Mn]1N2C3=CC=C2C(C2=CC=CC=C2)=C2C=CC(=N2)/C(C2=CC=CC=C2)=C2/C=CC(N12)=C(C1=NC(C=C1)=C/3C1=CC=CC=C1)C1=CC=CC=C1

Molecular Weight

726.702

Molecular Formula

C46H31MnN4O2

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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