Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride

Product Number: T40169; CAS Number: 79968-43-7

SDS

$166.00$275.00

$166.00
$275.00

Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride CAS: 79968-43-7 MDL: MFCD09038963

SDS

Molecular weight: 1062.92 g/mol

Molecular Formula: C44H8ClF20MnN4

CAS Number: 79968-43-7

Storage: Store at room temperature, protect from light.

Synonyms: Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride, 79968-43-7, MFCD09038963

Fields of Interest: Catalysis, Cytochrome P450 mimics, Sensors

Background: Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride was used to modify electrode surfaces for the detection of cysteine.1 Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride was functionalized to produce a biocompatible redox MRI probe.2 Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride is used for catalytic oxidation, including C-H activation.3-5

References:

1.) Gallo, et al. The use of modified electrodes by hybrid systems gold nanoparticles/Mn-porphyrin in electrochemical detection of cysteineSynthetic Metals. Volume 198, December 2014, Pages 335-339. https://doi.org/10.1016/j.synthmet.2014.10.024

2.) Pinto, et al. A biocompatible redox MRI probe based on a Mn(ii)/Mn(iii) porphyrin. Dalton Trans., 2019,48, 3249-3262. https://doi.org/10.1039/C8DT04775H

3.) Battioni, et al.An easy access to polyhalogenated metalloporphyrins covalently bound to polymeric supports as efficient catalysts for hydrocarbon oxidation. J. Chem. Soc., Chem. Commun., 1992, 1051-1053. https://doi.org/10.1039/C39920001051

4.) Jung, et al. Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2with Manganese PorphyrinsJ. Phys. Chem. A 2014, 118, 32, 6223–6229. https://doi.org/10.1021/jp505860f

5.) Yu, et al. Amidation of Saturated C−H Bonds Catalyzed by Electron-Deficient Ruthenium and Manganese Porphyrins. A Highly Catalytic Nitrogen Atom Transfer Process. Org. Lett. 2000, 2, 15, 2233–2236. https://doi.org/10.1021/ol000107r

 

Categories

Functional Groups

,

Metal

Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

Purity %

>95%

Molecular Formula

C44H8ClF20MnN4

Molecular Weight

1062.92

CAS #

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