5-mono(4-carboxyphenyl)-10,15,20-triphenyl porphyrin monomethyl ester

5-mono(4-carboxyphenyl)-10,15,20-triphenyl porphyrin monomethyl ester CAS: 119730-06-2 MDL: MFCD02093480

Molecular weight: 672.77 g/mol

Molecular Formula: C₄₆H₃₂N₄O₂

CAS Number: 119730-06-2

Storage: Store at room temperature, protect from light.

Synonyms: Methyl-4-(10,15,20-triphenyl-5-porphyrinyl)benzoat, 119730-06-2, 5-(4-METHOXYCARBONYLPHENYL)-10,15,20-TRIPHENYL-21,23H-PORPHYRIN, 5-(4-METHOXYCARBONYLPHENYL)-10,15,20-TRIPHENYL-21H,23H-PORPHINE, 5-(4-Methoxycarbonylphenyl)-10,15,20-triphenylporphyrin, MFCD02093480

Fields of Interest: Synthetic Porphyrins, Mono Functionalized Porphyrins,

Background: 5-mono(4-carboxyphenyl)-10,15,20-triphenyl porphyrin monomethyl ester is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. 5-mono(4-carboxyphenyl)-10,15,20-triphenyl porphyrin monomethyl ester is a useful starting material for the construction of mono-functionalized porphyrins.^1-4

References: 

1.) Carrie, et al. Synthesis and chemical reactivity of new zinc porphyrin diazoacetates catalyzed by ruthenium and iron porphyrins. Tetrahedron Letters. Volume 57, Issue 10, 9 March 2016, Pages 1179-1182. https://doi.org/10.1016/j.tetlet.2016.02.010

2.) Shekar, et al. Synthesis and fluorescence studies of porphyrin appended 1,3,4-oxadiazoles. Journal of Porphyrins and Phthalocyanines Vol. 14, No. 12, pp. 1034-1039 (2010). https://doi.org/10.1142/S1088424610002884

3.) Panagiotakis, et al. Increased Efficiency of Dye-Sensitized Solar Cells by Incorporation of a π Spacer in Donor–Acceptor Zinc Porphyrins Bearing Cyanoacrylic Acid as an Anchoring Group. EurJIC, Volume 2018, Issue 20-21, June 7, 2018, Pages 2369-2379. https://doi.org/10.1002/ejic.201800123

4.) Proni, et al. Magnesium Tetraarylporphyrin Tweezer:  a CD-Sensitive Host for Absolute Configurational Assignments of α-Chiral Carboxylic Acids. J. Am. Chem. Soc. 2003, 125, 42, 12914–12927. https://doi.org/10.1021/ja036294g