Pd(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin

Product Number: F12864; CAS Number: 1092095-11-8

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Pd(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin CAS: 1092095-11-8 MDL: MFCD22377389

Molecular weight: 991.34 g/mol

Molecular Formula: C60H32F4N4Pd

CAS Number: 1092095-11-8

Storage: Store at room temperature, protect from light.

Synonyms: Pd(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin, 1092095-11-8, MFCD22377389

Fields of Interest: Synthetic Porphyrins, Palladium Porphyrins, Triplet-Triplet Upconversion, Photoredox Catalysis, Sensors

Background: Pd(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Niedermair, et al. Tunable Phosphorescent NIR Oxygen Indicators Based on Mixed Benzo- and Naphthoporphyrin Complexes. Inorg. Chem. 2010, 49, 20, 9333–9342. https://doi.org/10.1021/ic100955z

2.) Borisov, et al. New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins. Journal of Photochemistry and Photobiology A: Chemistry. Volume 201, Issues 2–3, 25 January 2009, Pages 128-135. https://doi.org/10.1016/j.jphotochem.2008.10.003

3.) Ehgartner, et al. Online analysis of oxygen inside silicon-glass microreactors with integrated optical sensors. Sensors and Actuators B: Chemical. Volume 228, 2 June 2016, Pages 748-757. https://doi.org/10.1016/j.snb.2016.01.050

4.) Monguzzi, et al. Efficient Broadband Triplet–Triplet Annihilation-Assisted Photon Upconversion at Subsolar Irradiance in Fully Organic Systems. Advanced Functional Materials. Volume 25, Issue 35, September 16, 2015, Pages 5617-5624. https://doi.org/10.1002/adfm.201502507

5.) Kwak, et al. Deactivation of redox mediators in lithium-oxygen batteries by singlet oxygen. Nat Commun 10, 1380 (2019). https://doi.org/10.1038/s41467-019-09399-0

6.) Borisov, et al. Red Light-Excitable Oxygen Sensing Materials Based on Platinum(II) and Palladium(II) Benzoporphyrins. Anal. Chem. 2008, 80, 24, 9435–9442. https://doi.org/10.1021/ac801521v

Categories

Porphyrins

Functional Groups

fluorine, Fluoro, Phenyl And Aromatic Rings

Metal

Palladium Porphyrins

Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives, Tetrabenzo Porphyrins

Porphyrin Substitution

Meso And Beta Substituted Porphyrins, Phenyl Substituted Porphyrins

Purity %

>95%

Molecular Formula

C60H32F4N4Pd

Molecular Weight

991.34

CAS #

1092095-11-8

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