Ni(II) meso-Tetra (4-pyridyl) porphine

Ni(II) meso-Tetra (4-pyridyl) porphine CAS: 14514-68-2 MDL: MFCD00698433

Molecular weight: 675.37 g/mol

Molecular Formula: C₄₀H₂₄N₈Ni

CAS Number: 14514-68-2

Storage: Store at room temperature, protect from light.

Synonyms: Ni(II) meso-Tetra (4-pyridyl) porphine, 21H,23H-Porphine, 5,10,15,20-tetra-4-pyridinyl-, nickel salt (1:1), 5,10,15,20-Tetra(4-pyridinyl)porphyrin – nickel (1:1), 5,10,15,20-Tetra(4-pyridinyl)porphyrin -nickel (1:1), 5,10,15,20-Tétra(4-pyridinyl)porphyrine – nickel (1:1), 14514-68-2, 5,10,15,20-Tetra(4-pyridyl)-21H,23H-porphyrin nickel

Fields of Interest: Synthetic Porphyrins, Catalysis, Metal-Organic Frameworks, Non-Linear Optics, Thin-Films

Background: Ni(II) meso-Tetra (4-pyridyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Kadish, et al. Electrochemical and spectroelectrochemical studies of nickel(II) porphyrins in dimethylformamide. Inorganic Chemistry, 1988, vol. 27, # 7, p. 1198 – 1204. https://doi.org/10.1021/ic00280a021

2.) Li, et al. Interpenetrated Metal-Porphyrinic Framework for Enhanced Nonlinear Optical Limiting. Journal of the American Chemical Society, 2021, vol. 143, # 41, p. 17162 – 17169. https://doi.org/10.1021/jacs.1c07803

3.) Barbosa, et al. Nonlinear absorption dynamics in tetrapyridyl metalloporphyrins. Journal of Physical Chemistry B, 2005, vol. 109, # 36, p. 17340 – 17345. https://doi.org/10.1021/jp052168i

4.) Garcia, et al. Synthesis, spectral, electrochemical and flash photolysis studies of Fe(II), Ni(II) tetrapyridylporphyrins coordinated at the periphery with chromium(III) phenanthroline complexes. Inorganica Chimica Acta, 2012, vol. 386, p. 73 – 82. https://doi.org/10.1016/j.ica.2012.02.023

5.) Tomita, et al. Control of supramolecular organizations by coordination bonding in tetrapyridylporphyrin thin films. Chemical Communications, 2022, vol. 58, # 13, p. 2116 – 2119. https://doi.org/10.1039/D1CC06169K