Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride

Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride CAS: 125565-45-9 MDL: MFCD00274660

SDS

Molecular weight: 909.013g/mol

Molecular Formula: C₄₄H₃₆Cl₅MnN₈

CAS Number: 125565-45-9

Storage: Store at room temperature, protect from light

Synonyms: Chloro[5,10,15,20-tetra(4-pyridinyl)porphyrinato(2-)-κ²N²¹,N²³]manganese – chloromethane (1:4), Chlor[5,10,15,20-tetra(4-pyridinyl)porphyrinato(2-)-κ²N²¹,N²³]mangan -chlormethan (1:4), Chloro[5,10,15,20-tetra(4-pyridinyl)porphyrinato(2-)-κ²N²¹,N²³]manganese – chloromethane (1:4), Chloro[5,10,15,20-tétra(4-pyridinyl)porphyrineato(2-)-κ²N²¹,N²³]manganèse – chlorométhane (1:4), Manganese, chloro[5,10,15,20-tetra-4-pyridinyl-21H,23H-porphinato(2-)-κN²¹,κN²³]-, compd. with chloromethane (1:4), 125565-45-9, MFCD00274660

Field of Interest: Water Soluble Porphyrins, Catalysis, Sensors

Background: Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride was used as an non-enzymatic sensor for and the electrochemical reduction of hydrogen peroxide.^1,2 Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride was used for the electrocatalytic reduction of dioxygen.³ Mn(III) meso-Tetra (N-methyl-4-pyridyl) porphine pentachloride was incorporated into a hydrogel and its catalytic properties were reported.⁴

References: 

1.) Peng, et al. Biomimetic sensor based on Mn(III) meso-tetra(N-methyl-4-pyridyl) porphyrin for non-enzymatic electrocatalytic determination of hydrogen peroxide and as an electrochemical transducer in oxidase biosensor for analysis of biological media. Sensors and Actuators B: Chemical. Volume 321, 15 October 2020, 128437. https://doi.org/10.1016/j.snb.2020.128437

2.) Mourzina, et al. Electrochemical properties and biomimetic activity of water-soluble meso-substituted Mn(III) porphyrin complexes in the electrocatalytic reduction of hydrogen peroxide. Journal of Electroanalytical Chemistry. Volume 866, 1 June 2020, 114159. https://doi.org/10.1016/j.jelechem.2020.114159

3.) Lieske, et al. Electrocatalytic reduction of dioxygen by Mn(iii) meso-tetra(N–methylpyridinium-4-yl)porphyrin in universal buffer. Dalton Trans., 2019,48, 8633-8641. https://doi.org/10.1039/C9DT01436E

4.) Maddahzadeh-Darini, N., Ghorbanloo, M. Supra-Amphiphilic Porphyrin Based on Thermoresponsive Poly(N-Isopropylacrylamide-co-2-Acrylamido-2-Methylpropane Sulfonic Acid Sodium) Hydrogels: Synthesis, Characterization and Catalytic Applications. Catal Lett (2022). https://doi.org/10.1007/s10562-022-04241-7

5.) : Mourzina YG, Ermolenko YE and Offenhäusser A (2021) Synthesizing Electrodes Into Electrochemical Sensor Systems. Front. Chem. 9:641674. doi: 10.3389/fchem.2021.641674

6.) Petrova, et al. Binding of Antitumor Compounds to Wheat Protein. Biotechnology & Biotechnological Equipment. Volume 27, 2013 – Issue 3, Pages 3857-3860 . https://doi.org/10.5504/BBEQ.2013.0025

7.) Khan, et al. Nanomedical studies of the restoration of nitric oxide/peroxynitrite balance in dysfunctional endothelium by 1,25-dihydroxy vitamin D₃ – clinical implications for cardiovascular diseases. Int J Nanomedicine. 2018; 13: 455–466. https://doi.org/10.2147/IJN.S152822