meso-Tetra (4-fluorophenyl) porphine

meso-Tetra (4-fluorophenyl) porphine CAS: 37095-43-5 MDL: MFCD01941197

Molecular weight: 686.70 g/mol

Molecular Formula: C₄₄H₂₆F₄N₄

CAS Number: 37095-43-5

Storage: Store at room temperature, protect from light.

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(4-fluorophenyl)-, 37095-43-5, 5,10,15,20-Tetrakis(4-fluorophenyl)porphyrin, 5,10,15,20-Tétrakis(4-fluorophényl)porphyrine, 5,10,15,20-Tetrakis(4-fluorphenyl)porphyrin, 5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE, 5,10,15,20-TETRAKIS(4-FLUOROPHENYL)-21H,23H-PORPHINE), 5,10,15,20-tetrakis-(p-fluorophenyl)porphyrin, MFCD01941197

Fields of Interest: Synthetic Porphyrins, Halogenated Porphyrins

Background: meso-Tetra (4-fluorophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Zhu, et al. Effect of substituent groups of porphyrins on the electroluminescent properties of porphyrin-doped OLED devices. Journal of Physical Organic Chemistry. Volume 23, Issue 3, March 2010, Pages 190-194.

2.) Ikeda, et al. Allosteric Binding of an Ag⁺ Ion to Cerium(IV) Bis-porphyrinates Enhances the Rotational Activity of Porphyrin Ligands. Chemistry A European Journal. Volume 8, Issue 24, December 16, 2002, Pages 5541-5550. https://doi.org/10.1002/1521-3765(20021216)8:24<5541::AID-CHEM5541>3.0.CO;2-X

3.) Espitia-Almeida, F., Díaz-Uribe, C., Vallejo, W. et al. Photophysical characterization and in vitro anti-leishmanial effect of 5,10,15,20-tetrakis(4-fluorophenyl) porphyrin and the metal (Zn(II), Sn(IV), Mn(III) and V(IV)) derivatives. Biometals 35, 159–171 (2022). https://doi.org/10.1007/s10534-021-00357-2

4.) Dar, et al. UV–visible and fluorescence spectroscopic assessment of meso‑tetrakis‑(4‑halophenyl) porphyrin; H₂TXPP (X = F, Cl, Br, I) in THF and THF-water system: Effect of pH and aggregation behaviour. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. Volume 240, 15 October 2020, 118570. https://doi.org/10.1016/j.saa.2020.118570

5.) Dhifaoui, et al. Synthesis, Mössbauer, cyclic voltammetry, magnetic properties and molecular structures of the low-spin iron(III) bis(pyrazine) complexes with the para-fluoro and para-chloro substituted meso-tetraphenylporphyrin. Inorganica Chimica Acta. Volume 477, 24 May 2018, Pages 114-121. https://doi.org/10.1016/j.ica.2018.02.016

6.) Yaman, et al. Synthesis of novel single site tin porphyrin complexes and the catalytic activity of tin tetrakis(4-fluorophenyl)porphyrin over 𝜀-caprolactone. Journal of Porphyrins and Phthalocyanines. Vol. 21, No. 03, pp. 231-237 (2017).  https://doi.org/10.1142/S1088424617500407