Fe(III) meso-Tetra(4-N,N,N- trimethylanilinium) Porphine Pentachloride

Product Number: 41062; CAS Number: 2241100-95-6

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Fe(III) meso-Tetra(4-N,N,N- trimethylanilinium) Porphine Pentachloride CAS: 2241100-95-6 MDL: MFCD32267987

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Molecular weight: 1078.24 g/mol

Molecular Formula: C56H60Cl5FeN

CAS Number: 2241100-95-6

Storage: Store at room temperature, protect from light.

Purity: >95%

Synonyms: Fe(III) meso-Tetra(4-N,N,N- trimethylanilinium) Porphine Pentachloride, 2241100-95-6, MFCD32267987, FeTMA

Fields of Interest: Synthetic Porphyrins, Iron Porphyrins, Water Soluble Porphyrins, Catalysis, Catalytic CO2 Reduction

Background: Fe(III) meso-Tetra(4-N,N,N- trimethylanilinium) Porphine Pentachloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Fe(III) meso-Tetra(4-N,N,N- trimethylanilinium) Porphine Pentachloride  has been investigated for the photochemical reduction of CO2 to CO and CH4.1-3

References:

1.) Lian, et al. Photocatalytically Active Superstructures of Quantum Dots and Iron Porphyrins for Reduction of CO2 to CO in Water. ACS Nano 2018, 12, 1, 568–575. https://doi.org/10.1021/acsnano.7b07377

2.) Rao, et al. Visible-light Homogeneous Photocatalytic Conversion of CO2 into CO in Aqueous Solutions with an Iron Catalyst. ChemSusChem. Volume 10, Issue 22, November 23, 2017, Pages 4447-4450.

3.) Rao, et al. Visible-Light-Driven Conversion of CO2 to CH4 with an Organic Sensitizer and an Iron Porphyrin Catalyst.  J. Am. Chem. Soc. 2018, 140, 51, 17830–17834. https://doi.org/10.1021/jacs.8b09740

 

 

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[2241100-95-6]

Purity %

>95%

Smiles

[Cl-].[Cl-].[Cl-].[Cl-].C[N+](C)(C)C1=CC=C(C=C1)C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Fe](Cl)N23)C1=CC=C(C=C1)[N+](C)(C)C)C1=CC=C(C=C1)[N+](C)(C)C)C1=CC=C(C=C1)[N+](C)(C)C

Molecular Weight

1078.24

Molecular Formula

C56H60Cl5FeN8

Functional Groups

Quaternary Ammonium

Metal

Iron Porphyrins

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives, Water Soluble Porphyrins

Porphyrin Substitution

Amino-Phenyl Substituted Porphyrins, Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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