meso-Octamethylcalix(4)pyrrole

meso-Octamethylcalix(4)pyrrole CAS: 4475-42-7 MDL: MFCD00208353

Molecular weight: 428.61 g/mol

Molecular Formula: C₂₈H₃₆N₄

CAS Number: 4475-42-7

Storage: Store at room temperature, protect from light.

Synonyms: 21H,23H-Porphine, 5,10,15,20,22,24-hexahydro-5,5,10,10,15,15,20,20-octamethyl-, 4475-42-7, 5,5,10,10,15,15,20,20-Octamethyl-5,10,15,20,22,24-hexahydroporphyrin, 5,5,10,10,15,15,20,20-Octamethyl-5,10,15,20,22,24-e]hexahydroporphyrin, 5,5,10,10,15,15,20,20-Octaméthyl-5,10,15,20,22,24-hexahydroporphyrine, meso-Octamethylcalix(4)pyrrole, meso-octamethylcalix[4]pyrrole, meso-octamethylporphyrinogen, MFCD00208353, 365398, 5,5,10,10,15,15,20,20-octamethyl-21,22,23,24-tetrahydroporphyrin, calix[4]pyrrole

Fields of Interest: Synthetic Porphyrins, Macrocyclic Ligands, Porphyrinogens, Sensors, Ion-Pair Receptors

Background: meso-Octamethylcalix(4)pyrrole is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. meso-Octamethylcalix(4)pyrrole is useful as an ion binding agent and as a ligand.

References:

1.) Gale, et al. Calix[4]pyrroles:  Old Yet New Anion-Binding Agents. J. Am. Chem. Soc. 1996, 118, 21, 5140–5141. https://doi.org/10.1021/ja960307r

2.) Wintergerst, et al. Calix[4]pyrrole:  A New Ion-Pair Receptor As Demonstrated by Liquid−Liquid Extraction. J. Am. Chem. Soc. 2008, 130, 12, 4129–4139. https://doi.org/10.1021/ja7102179

3.) Amharar, et al. Highly sensitive and cost-effective fluorescent turn-on sensors based on octamethylcalix[4]pyrrole receptor for the detection of fluoride anion. Dyes and Pigments. Volume 197, January 2022, 109918. https://doi.org/10.1016/j.dyepig.2021.109918

4.) Ruppert, et al. Calix[4]pyrrolato Stannate(II): A Tetraamido Tin(II) Dianion and Strong Metal-Centered σ-Donor. Angew. Chemie. Int.Ed. Volume 61, Issue 13, March 21, 2022. e202116615. https://doi.org/10.1002/anie.202116615

5.) Coskun, et al. Development of Highly Luminescent Water-Insoluble Carbon Dots by Using Calix[4]pyrrole as the Carbon Precursor and Their Potential Application in Organic Solar Cells. ACS Omega 2022, 7, 22, 18840–18851. https://doi.org/10.1021/acsomega.2c01795

6.) Ji, et al. Soft Materials Constructed Using Calix[4]pyrrole- and “Texas-Sized” Box-Based Anion Receptors. Acc. Chem. Res. 2019, 52, 7, 1915–1927. https://doi.org/10.1021/acs.accounts.9b00187