5,10-Diphenyl-15,20-di(4-pyridyl)-21H,23H-porphine

5,10-Diphenyl-15,20-di(4-pyridyl)-21H,23H-porphine CAS: 71410-73-6 MDL: MFCD16628186

Molecular weight: 616.712 g/mol

Molecular Formula: C₄₂H₂₈N₆

CAS Number: 71410-73-6

Storage: Store at room temperature, protect from light.

Synonyms: 2,17-diphenyl-7,12-bis(pyridin-4-yl)-21,22,23,24-tetraazapentacyclo[16.2.1.1³,?.1?,¹¹.1¹³,¹?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 21H,23H-Porphine, 5,10-diphenyl-15,20-di-4-pyridinyl-, 5,10-Diphenyl-15,20-di(4-pyridinyl)porphyrin, 5,10-Diphenyl-15,20-di(4-pyridinyl)porphyrin, 5,10-Diphényl-15,20-di(4-pyridinyl)porphyrine, 71410-73-6, 5,10-bis(4 pyridyl)-15,20-diphenylporphyrin, 5,10-di(4-pyridyl)-15,20-diphenylporphyrin, 5,10-Diphenyl-15,20-di(4-pyridyl)-21H,23H-porphine, MFCD16628186

Fields of Interest: Synthetic Porphyrins, Cis A2B2 Porphyrins, Pyridyl Substituted Porphyrins, Coordination Chemistry, Self-Assembly

Background: 5,10-Diphenyl-15,20-di(4-pyridyl)-21H,23H-porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. 5,10-Diphenyl-15,20-di(4-pyridyl)-21H,23H-porphine is useful for the construction of supramolecular complexes.

References: 

1.) Vidal, et al. A Flexible Synthetic Strategy for the Preparation of Heteroleptic Metallacycles of Porphyrins. Inorg. Chem. 2021, 60, 15, 11503–11513. https://doi.org/10.1021/acs.inorgchem.1c01511

2.) Drain, et al. Self-assembly of square multiporphyrin arrays by metal ion coordination. J. Chem. Soc., Chem. Commun., 1994, 2313-2315. https://doi.org/10.1039/C39940002313

3.) Lengo, et al. A Functionalized Noncovalent Macrocyclic Multiporphyrin Assembly from a Dizinc(II) Bis-Porphyrin Receptor and a Free-Base Dipyridylporphyrin. Chemistry, A European Journal. Volume 9, Issue 23, December 5, 2003, Pages 5879-5887. https://doi.org/10.1002/chem.200304795

4.) Zhang, et al. A Discrete Platinum(II) Amphiphile: Construction, Characterization, and Controllable Self-Assembly in Different Solvents. Inorg. Chem. 2020, 59, 12, 7924–7927. https://doi.org/10.1021/acs.inorgchem.0c01164

5.) Horiguchi, et al. Controllable Direction of Porphyrin Derivatives in Two Cyclodextrin Cavities. EurJOC. Volume 2018, Issue 18, May 15, 2018, Pages 2138-2143. https://doi.org/10.1002/ejoc.201800433