Zn(II) meso-Tetra(4-pyridyl) Porphine

Product Number: T41135; CAS Number: 31183-11-6

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Zn(II) meso-Tetra(4-pyridyl) Porphine CAS: 31183-11-6 MDL: MFCD00274658

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Molecular weight: 682.081 g/mol

Molecular Formula: C40H24N8Zn

CAS Number: 31183-11-6

Storage: Store at room temperature, protect from light

Synonyms: [5,10,15,20-Tetra(4-pyridinyl)porphyrinato(2-)-κ2N21,N23]zinc, [5,10,15,20-Tetra(4-pyridinyl)porphyrinato(2-)-κ2N21,N23]zink, [5,10,15,20-Tétra(4-pyridinyl)porphyrineato(2-)-κ2N21,N23]zinc, 31183-11-6, MFCD00274658, Zinc, [5,10,15,20-tetra-4-pyridinyl-21H,23H-porphinato(2-)-κN21,κN23], Zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine, Zn(II) meso-Tetra(4-pyridyl) Porphine, ZnTPyP

Field of Interest: Coordination Polymers, Self Assembly, Nanostructures, Covalent Organic Frameworks, Photosensitizers, Catalysis

Background: Zn(II) meso-Tetra(4-pyridyl) Porphine is a synthetic  porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. The spectroscopy of Zn(II) meso-Tetra(4-pyridyl) Porphine has been reported.1

References:

1.) Makhlouf, et al. Impact of Zn2+ introduced into the central cavity of meso-tetra(4-pyridyl)porphine on its spectroscopic features. Optical Materials. Volume 113, March 2021, 110893

2.) Cai, et al. Enhanced Electrochemiluminescence of One-Dimensional Self-Assembled Porphyrin Hexagonal Nanoprisms. ACS Appl. Mater. Interfaces 2017, 9, 24, 20904–20912. https://doi.org/10.1021/acsami.7b05188

3.) Bai, et al. Porous One-Dimensional Nanostructures through Confined Cooperative Self-Assembly. Nano Lett. 2011, 11, 12, 5196–5200. https://doi.org/10.1021/nl203598n

4.) Wang, et al. Synthesis of Self-Assembled Porphyrin Nanoparticle Photosensitizers. ACS Nano 2018, 12, 4, 3796–3803. https://doi.org/10.1021/acsnano.8b01010

5.) Wang, et al. Adsorption of DNA Oligonucleotides by Self-Assembled Metalloporphyrin Nanomaterials. Langmuir 2022, 38, 11, 3553–3560 https://doi.org/10.1021/acs.langmuir.2c00108

6.) Gera, et al. Metal-ions linked surface-confined molecular dyads of Zn-porphyrin–metallo-terpyridine: an experimental and theoretical study. RSC Adv., 2017, 7, 1290-1298. 10.1039/C6RA25090D 

7.) Hasobe, et al. Remarkable Enhancement of Photocatalytic Hydrogen Evolution Efficiency Utilizing An Internal Cavity of Supramolecular Porphyrin Hexagonal Nanocylinders Under  Visible-Light Irradiation. J. Phys. Chem. C 2013, 117, 9, 4441–4449. https://doi.org/10.1021/jp400381h

8.) Xu, et al. Hybrid hexagonal nanorods of metal nitride clusterfullerene and porphyrin using a supramolecular approach. J. Mater. Chem., 2011,21, 13538-13545. https://doi.org/10.1039/C1JM11801C

Categories

Porphyrins
Scaffold/Subcategory

Synthetic Porphyrins
CAS #

[31183-11-6]
Purity %

>95%
Smiles

[Zn]1N2C3=CC=C2C(C2=CC=NC=C2)=C2C=CC(=N2)/C(C2=CC=NC=C2)=C2/C=CC(N12)=C(C1=NC(C=C1)=C/3C1=CC=NC=C1)C1=CC=NC=C1
Molecular Weight

682.081
Molecular Formula

C40H24N8Zn
Functional Groups

Nitrogen Heterocycle
Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives
Porphyrin Substitution

Meso-Substituted Porphyrins, Pyridyl Substituted Porphyrins

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