Pt(II) Octaethylporphine (PtOEP)

Pt(II) Octaethylporphine (PtOEP) 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine,platinum(II) CAS: 31248-39-2 MDL: MFCD00672301

SDS

Molecular weight: 727.84 g/mol

Molecular Formula: C₃₆H₄₄N₄Pt

CAS Number:  31248-39-2

Storage: Store at room temperature, protect from light

Synonyms:  31248-39-2,  Pt(II) Octaethylporphine(PtOEP),  AKOS015963121, [2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ²N²¹,N²³]platin,[2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ²N²¹,N²³]platinum, [2,3,7,8,12,13,17,18-Octaéthylporphyrineato(2-)-κ²N²¹,N²³]platine, MFCD00672301, platinum octaethylporphyrin, Platinum(II) 2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphyrin, Platinum, [2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-κN²¹,κN²³]- , PtOEP, 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine platinum, 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine platinum(II), 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine,platinum(II), Pt(II) Octaethylporphine (PtOEP)

Field of Interest: Photo-Optics, Phosphorescent Energy Transfer, LEDs, Oxygen Sensor

Background: Pt(II) Octaethylporphine (PtOEP) is a porphyrin  based synthetic product that possesses phosphorescent properties and is a probe of triplet behavior and useful in energy transfer and electrophosphorescent devices. ^1,2   It also is useful in polymer LEDs as an efficient triplet emitter, and as a stable optical oxygen sensor. ^3,4

References: 

1.)  Baldo, M. A.; O’Brien, D. F.; You, Y.; Shoustikov, A.; Sibley, S.; Thompson, M. E.; Forrest, S. R, Highly efficient phosphorescent emission from organic electroluminescent devices, Nature (London) (1998), 395(6698), 151-154.

2.)  O’Brien, D. F.; Baldo, M. A.; Thompson, M. E.; Forrest, S. R., Improved energy transfer in electrophosphorescent devices, Applied Physics Letters (1999), 74(3), 442-444.

3.)  Cleave, Vicki; Yahioglu, Goghan; Le Barny, Pierre; Friend, Richard H.; Tessler, Nir, Harvesting singlet and triplet energy in polymer LEDs, Advanced Materials (Weinheim, Germany) (1999), 11(4), 285-288.

4.)  Palma, Alberto J.; Lopez-Gonzalez, Javier; Asensio, Luis J.; Fernandez-Ramos, Maria Dolores; Capitan-Vallvey, Luis Fermin, Microcontroller-based portable instrument for stabilized optical oxygen sensor, Sensors and Actuators, B: Chemical (2007), 121(2), 629-638