Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin

Product Number: F12863; CAS Number: 1092095-10-7

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Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin CAS: 1092095-10-7 MDL: MFCD22377325

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Molecular weight: 1080.00 g/mol

Molecular Formula: C60H32F4N4Pt

CAS Number: 1092095-10-7

Storage: Store at room temperature, protect from light

Synonyms: Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin CAS: 1092095-10-7 MDL: MFCD22377325, PtTPTBPF

Field of Interest: Phosphorescent Oxygen Sensors, Triplet-Triplet Annihilation, Photon Upconversion

Background: Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin displays highly efficient room-temperature NIR phosphorescence, with improved photostability and utility in oxygen sensors.1 Pt(II) meso-Tetra(4-fluorophenyl)tetrabenzoporphyrin was used for non-invasive Real-Time Oxygen Biosensing in Two- and Three-Dimensional Microfluidic Cell Models.2 Platinum (II)-meso-tetra (4-fluorophenyl) tetrabenzoporphyrin has peak absorption at 430 and 614 nm and peak emission at 733 nm.3

References: 

1.) Borisov, et al. New NIR-emitting complexes of platinum(II) and palladium(II) with fluorinated benzoporphyrins. Journal of Photochemistry and Photobiology A: Chemistry. Volume 201, Issues 2–3, 25 January 2009, Pages 128-135. https://doi.org/10.1016/j.jphotochem.2008.10.003

2.) Zirath, et al. Every Breath You Take: Non-invasive Real-Time Oxygen Biosensing in Two- and Three-Dimensional Microfluidic Cell Models. Front. Physiol., 03 July 2018
Sec. Integrative Physiology. Volume 9 – 2018 https://doi.org/10.3389/fphys.2018.00815

3.) Najdahmadi, et al. Oxygen Monitor to Study Vascularization of Medical Devices.MRS Advances , Volume 5 , Issue 18-19: Soft Materials and Biomaterials , 2020 , pp. 991 – 1000 https://doi.org/10.1557/adv.2020.97

4.) Borisov, et al. Indicators for optical oxygen sensors. Advances in Chemical Bioanalysis pp 1–70. 

5.) Barbieri, et al. The Rise of Near-Infrared Emitters: Organic Dyes, Porphyrinoids, and Transition Metal Complexes. Photoluminescent Materials and Electroluminescent Devices pp 269–307.

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[1092095-10-7]

Purity %

>95%

Smiles

Not Applicable

Molecular Weight

1080

Molecular Formula

C60H32F4N4Pt

Functional Groups

fluorine, Fluoro, Phenyl And Aromatic Rings

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives, Tetrabenzo Porphyrins

Porphyrin Substitution

Meso And Beta Substituted Porphyrins, Phenyl Substituted Porphyrins

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