Pd(II) meso-Tetra(4-carboxyphenyl)porphine

Pd(II) meso-Tetra(4-carboxyphenyl)porphine meso-Tetraphenylporphine- 4,4′,4”,4”’-tetracarboxylic acid, palladium(II) CAS: 94288-44-5 MDL: MFCD00672300

SDS

Molecular weight: 895.18 g/mol 

Molecular Formula: C₄₈H₂₈N₄O₈Pd                      

CAS Number:  94288-44-5

Storage: Store at room temperature, protect from light

Synonyms: 94288-44-5, PD(II) MESO-TETRA(4-CARBOXYPHENYL)PORPHINE, CS-0111518, [4,4′,4”,4”’-(5,10,15,20-Porphyrinetétrayl-κ²N²¹,N²³)tetrabenzoato(2-)]palladium, [4,4′,4”,4”’-(5,10,15,20-Porphyrintetrayl-κ²N²¹,N²³)tetrabenzoato(2-)]palladium, [4,4′,4”,4”’-(5,10,15,20-Porphyrintetrayl-κ²N²¹,N²³)tetrabenzoato(2-)]palladium, Palladium, [4,4′,4′‘,4”’-(21H,23H-porphine-5,10,15,20-tetrayl-κN²¹,κN²³)tetrakis[benzoato](2-)]-, meso-Tetraphenylporphine- 4,4′,4”,4”‘-tetracarboxylic acid, palladium(II), MFCD00672300, Pd(II) meso-Tetra(4-carboxyphenyl)porphine

Field of Interest: Synthetic Porphyrin, Oxygen and Carbon Monoxide sensors, Hydrogels, Metal-Organic Frameworks, Metal Sensors 

Background: Pd(II) meso-Tetra(4-carboxyphenyl)porphine is a porphyrin  based synthetic specialty chemical product which possesses unique photophysical properties and is useful for the detection of oxygen and carbon monoxide, among many analytes. ^1,2   Pd(II) meso-Tetra(4-carboxyphenyl)porphine was incorporated into a hydrogel for the detection of lactate and for the production of metal organic frameworks for sensing. ^3,4

References:

1.)  Wilson, Reid L.; Connell, Jennifer P.; Grande-Allen, K. Jane, Monitoring Oxygen Levels within Large, Tissue-Engineered Constructs Using Porphyin-Hydrogel Microparticles, ACS Biomaterials Science & Engineering (2019), 5(9), 4522-4530. DOI:10.1021/acsbiomaterials.9b00257.

2.)  Zeng, Jin-Yue; Wang, Xiao-Shuang; Qi, Yong-Dan; Yu, Yun; Zeng, Xuan; Zhang, Xian-Zheng, Structural Transformation in Metal-Organic Frameworks for Reversible Binding of Oxygen, Angewandte Chemie, International Edition (2019), 58(17), 5692-5696. DOI:10.1002/anie.201902810.

3.)  Biswas, Aniket; Bornhoeft, Lindsey R.; Banerjee, Swayoma; You, Yil-Hwan; McShane, Michael J., Composite Hydrogels Containing Bioactive Microreactors for Optical Enzymatic Lactate Sensing, ACS Sensors (2017), 2(11), 1584-1588. DOI:10.1021/acssensors.7b00648.

4.)  Goswami, Subhadip; Chen, Michelle; Wasielewski, Michael R.; Farha, Omar K.; Hupp, Joseph T., Boosting Transport Distances for Molecular Excitons within Photoexcited Metal-Organic Framework Films, ACS Applied Materials & Interfaces (2018), 10(40), 34409-34417, DOI:10.1021/acsami.8b14977