Ni(II) Octaethylporphine

Product Number: NiO534; CAS Number: 24803-99-4

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Ni(II) Octaethylporphine 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine nickel(II) CAS: 24803-99-4 MDL: MFCD00010242

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Molecular weight: 591.455 g/mol

Molecular Formula: C36H44N4Ni

CAS Number: 24803-99-4

Storage: Store at room temperature, protect from light.

Synonyms:[2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ2N21,N23]nickel, [2,3,7,8,12,13,17,18-Octaethylporphyrinato(2-)-κ2N21,N23]nickel, [2,3,7,8,12,13,17,18-Octaéthylporphyrineato(2-)-κ2N21,N23]nickel, 24803-99-4, MFCD00010242, Nickel, [2,3,7,8,12,13,17,18-octaethyl-21H,23H-porphinato(2-)-κN21,κN23]-, 2,3,7,8,12,13,17,18-Octaethyl-21H,23H-porphine nickel(II), Ni(II) Octaethylporphine, octaethylphorphyrinato nickel

Fields of Interest: Catalysis, Photophysics, CoCrystallization

Background: Ni(II) Octaethylporphine is a synthetic porphyrin  specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Nandi, et al. Surface directed reversible imidazole ligation to nickel(ii) octaethylporphyrin at the solution/solid interface: a single molecule level study. Phys. Chem. Chem. Phys., 2016,18, 20819-20829. https://doi.org/10.1039/C6CP04454A

2.) Kruglik, et al. Time-resolved resonance Raman study of the primary photoprocesses of nickel(II) octaethylporphyrin in solution. Chemical Physics Letters. Volume 266, Issues 3–4, 28 February 1997, Pages 283-289.

3.) Balch, et al. Isolation and Crystallographic Characterization of Sm@C2v(3)-C80Through Cocrystal Formation with NiII(octaethylporphyrin) or Bis(ethylenedithio)tetrathiafulvalene. Inorg. Chem. 2013, 52, 3, 1275–1284. https://doi.org/10.1021/ic301794r

4.) Lexa, et al. Does one-electron transfer to nickel(II) porphyrins involve the metal or the porphyrin ligand? Inorg. Chem. 1989, 28, 1, 30–35. https://doi.org/10.1021/ic00300a009

5.) Bloodworth, et al. First Synthesis and Characterization of CH4@C60 Angew. Chemie. Int. ed. Volume 58, Issue 15, April 1, 2019, Pages 5038-5043. https://doi.org/10.1002/anie.201900983

Categories

Porphyrins

Functional Groups

Alkyl

Metal

Nickel Porphyrins

Porphyrin Family

Metallo Porphyrins, Octaethyl Porphyrins

Porphyrin Substitution

Alkyl Substituted Porphyrins, Beta Substituted Porphyrins

Purity %

>95%

Molecular Formula

C36H44N4Ni

Molecular Weight

591.45

CAS #

24803-99-4

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