Mn(III) meso-Tetraphenylporphine chloride (1-3% chlorin)

Product Number: T13881; CAS Number: 32195-55-4

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Mn(III) meso-Tetraphenylporphine chloride (1-3% chlorin) CAS: 32195-55-4 MDL: MFCD00012153, Chloride Ionophore i.

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Molecular weight: 703.111 g/mol

Molecular Formula: C44H28ClMnN4

CAS Number: 32195-55-4

Storage: Store at room temperature, protect from light.

Synonyms: 32195-55-4, Chlor[5,10,15,20-tetraphenylporphyrinato(2-)-κ2N21,N23]mangan, Chloride ionophore I, Chloro[5,10,15,20-tetraphenylporphyrinato(2-)-κ2N21,N23]manganese, Chloro[5,10,15,20-tétraphénylporphyrineato(2-)-κ2N21,N23]manganèse, Manganese, chloro[5,10,15,20-tetraphenyl-21H,23H-porphinato(2-)-κN21,κN23]-, meso-Tetraphenylporphyrin manganese(III) chloride complex, meso-Tetraphenylporphyrin manganese(III)-chloride complex, MFCD00012153, (5,10,15,20-tetraphenylporphinato)manganese(iii) chloride, 5,10,15,20-tetraphenyl-21H,23H-porphine manganese(iii) chloride, CHLORIDEIONOPHOREI, manganese tetraphenylporphyrin chloride

Fields of Interest: Synthetic Porphyrins, Ionophores, Sensors, Catalysis, Epoxidation, Thin Films

Background: Mn(III) meso-Tetraphenylporphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Mn(III) meso-Tetraphenylporphine chloride was used for the construction of thin films for optoelectronic applications.1-2, Mn(III) meso-Tetraphenylporphine chloride has been used for numerous catalytic applications, including epoxidation of olefins, hydrogen evolution, oxidative coupling.3-6 Mn(III) meso-Tetraphenylporphine chloride was also used as a probe for histidine using resonance light scattering.7

References:

1.) Al-Muntaser, et al. Tuning structural, optical, and dispersion functions of polystyrene via addition of meso-tetraphenylporphine manganese (III) chloride towards optoelectronic applications. Optical Materials, Volume 135, January 2023, 113333. https://doi.org/10.1016/j.optmat.2022.113333

2.) Attia, et al. Studies on structural and optical properties of thermally evaporated nanocrystalline thin films of meso-Tetraphenylporphyrin manganese(III) chloride. Journal of Luminescence. Volume 199, July 2018, Pages 391-399.

2.) Merlau, et al. Anthracene-Induced Turnover Enhancement in the Manganese Porphyrin-Catalyzed Epoxidation of Olefins. Inorg. Chem. 2005, 44, 15, 5523–5529. https://doi.org/10.1021/ic0505596

3.) Mahmoudi, et al. Water increases rates of epoxidation by Mn(iii)porphyrins/imidazole/IO4- in CH2Cl2. Analogy with peroxidase and chloride dismutase. Dalton Trans., 2011,40, 8695-8700. https://doi.org/10.1039/C1DT10689A

4.) Guo, et al. Spectroscopic observation of iodosylarene metalloporphyrin adducts and manganese(V)-oxo porphyrin species in a cytochrome P450 analogue. Nature Communications volume 3, Article number: 1190 (2012). https://doi.org/10.1038/ncomms2196

5.) Alzabny, et al. Mn(III) and Fe(III) Porphyrin Complexes as Electrocatalysts for Hydrogen Evolution Reaction: A comparative study.Int. J. Electrochem. Sci., 16 (2021). 10.20964/2021.07.24

6.) Yuan, et al. Efficient oxidative coupling of amines to imines catalyzed by manganese(III) meso-tetraphenylporphyrin chloride under ambient conditions. Catalysis Communications. Volume 12, Issue 3, 30 November 2010, Pages 202-206. https://doi.org/10.1016/j.catcom.2010.09.009

7.) Chen, et al. A novel histidine assay using tetraphenylporphyrin manganese (III) chloride as a molecular recognition probe by resonance light scattering technique. Analytica Chimica Acta. Volume 570, Issue 1, 7 June 2006, Pages 109-115. https://doi.org/10.1016/j.aca.2006.04.003

Categories

Porphyrins
Metal

Manganese Porphyrins
Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives
Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins
Purity %

>95%
Molecular Formula

C44H28ClMnN4
Molecular Weight

703.111
CAS #

32195-55-4

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