Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride CAS: 79968-43-7 MDL: MFCD09038963
Molecular weight: 1062.92Â g/mol
Molecular Formula:Â C44H8ClF20MnN4
CAS Number:Â 79968-43-7
Storage:Â Store at room temperature, protect from light.
Synonyms: Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride, 79968-43-7, MFCD09038963
Fields of Interest:Â Catalysis, Cytochrome P450 mimics, Sensors
Background: Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride was used to modify electrode surfaces for the detection of cysteine.1 Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride was functionalized to produce a biocompatible redox MRI probe.2 Mn(III) meso-Tetra(pentafluorophenyl) Porphine Chloride is used for catalytic oxidation, including C-H activation.3-5
References:
1.) Gallo, et al. The use of modified electrodes by hybrid systems gold nanoparticles/Mn-porphyrin in electrochemical detection of cysteine. Synthetic Metals. Volume 198, December 2014, Pages 335-339. https://doi.org/10.1016/j.synthmet.2014.10.024
2.) Pinto, et al. A biocompatible redox MRI probe based on a Mn(ii)/Mn(iii) porphyrin. Dalton Trans., 2019,48, 3249-3262. https://doi.org/10.1039/C8DT04775H
3.) Battioni, et al.An easy access to polyhalogenated metalloporphyrins covalently bound to polymeric supports as efficient catalysts for hydrocarbon oxidation. J. Chem. Soc., Chem. Commun., 1992, 1051-1053. https://doi.org/10.1039/C39920001051
4.) Jung, et al. Photocatalytic Oxygenation of 10-Methyl-9,10-dihydroacridine by O2with Manganese Porphyrins. J. Phys. Chem. A 2014, 118, 32, 6223–6229. https://doi.org/10.1021/jp505860f
5.) Yu, et al. Amidation of Saturated C−H Bonds Catalyzed by Electron-Deficient Ruthenium and Manganese Porphyrins. A Highly Catalytic Nitrogen Atom Transfer Process. Org. Lett. 2000, 2, 15, 2233–2236. https://doi.org/10.1021/ol000107r
