Mn(III) meso-Tetra (o-dichlorophenyl) porphine chloride

Product Number: T40532; CAS Number: 91463-17-1

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Mn(III) meso-Tetra (o-dichlorophenyl) porphine chloride CAS: 91463-17-1 MDL: MFCD06227756

Molecular weight: 993.71 g/mol

Molecular Formula: C45H23Cl9MnN4

CAS Number: 91463-17-1

Storage: Store at room temperature, protect from light.

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(2,6-dichlorophenyl)-, manganese(3+) salt, hydrochloride (1:1:1), Chlorure 5,10,15,20-tétrakis(2,6-dichlorophényl)porphine-21,23-diide de manganèse(3+) (1:1:1), Mangan(3+)chlorid-5,10,15,20-tetrakis(2,6-dichlorphenyl)porphin-21,23-diid (1:1:1), Manganese(3+) chloride 5,10,15,20-tetrakis(2,6-dichlorophenyl)porphine-21,23-diide (1:1:1), 91463-17-1, Manganese Tetrakis(2,6-dichlorophenyl)porphyrin Chloride

Fields of Interest: Synthetic Porphyrins, Catalysis, Cytochrome P450 mimics

Background: Mn(III) meso-Tetra (o-dichlorophenyl) porphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Battioni, et al. Monooxygenase-like Oxidation of Hydrocarbons by H2O2 Catalyzed by Manganese Pophyrins and Imidazole: Selection of the Best Catalytic System and Nature of the Active Oxygen Species. Journal of the American Chemical Society, 1988, vol. 110, # 25, p. 8462 – 8470. https://doi.org/10.1021/ja00233a023

2.) Mansuy, et al. Highly oxidation resistant inorganic-porphyrin analogue polyoxometalate oxidation catalysts. 2. Catalysis of olefin epoxidation and aliphatic and aromatic hydroxylations starting from α2-P2W17O61(M n+·Br)(n-11) (Mn+ = Mn3+, Fe3+, Co2+, Ni2+, Cu2+). Journal of the American Chemical Society, 1991, vol. 113, # 19, p. 7222 – 7226. https://doi.org/10.1021/ja00019a019

3.) Chan, et al. Oxidative amide synthesis and N-terminal α-amino group ligation of peptides in aqueous medium. Journal of the American Chemical Society, 2006, vol. 128, # 46, p. 14796 – 14797. https://doi.org/10.1021/ja064479s

4.) Guo, et al. Highly Reactive Manganese(IV)-Oxo Porphyrins Showing Temperature-Dependent Reversed Electronic Effect in C-H Bond Activation Reactions. Journal of the American Chemical Society, 2019, vol. 141, # 31, p. 12187 – 12191. https://doi.org/10.1021/jacs.9b04496

5.) Akagah, et al. Oxidation of antiparasitic 2-substituted quinolines using metalloporphyrin catalysts: Scale-up of a biomimetic reaction for metabolite production of drug candidates. Organic and Biomolecular Chemistry, 2008, vol. 6, # 24, p. 4494 – 4497. https://pubs.rsc.org/en/content/articlelanding/2008/OB/b815963g

6.) Zhang, et al. Unprecedented Reactivities of Highly Reactive Manganese(III)-Iodosylarene Porphyrins in Oxidation Reactions. Journal of the American Chemical Society, 2020, vol. 142, # 47, p. 19879 – 19884. https://doi.org/10.1021/jacs.0c10159

7.) Che, et al. Direct preparation of unprotected aminimides (R3N+-NH) from natural aliphatic tertiary alkaloids (R3N) by [Mn(TDCPP)Cl]-catalysed: N -amination reaction. Chemical Communications, 2020, vol. 56, # 64, p. 9102 – 9105. https://doi.org/10.1039/D0CC02934C

8.) Bhuvanesh, et al. Nitrene Photochemistry of Manganese N-Haloamides. Angewandte Chemie – International Edition, 2021, vol. 60, # 51, p. 26647 – 26655. https://doi.org/10.1002/anie.202108304

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[91463-17-1]

Purity %

>95%

Smiles

CN1C2=CC=C1C(=C1C=CC(=N1)/C(=C1/C=CC(N1[Mn]Cl)=C(C1=NC(C=C1)=C/2C1=C(Cl)C=CC=C1Cl)C1=C(Cl)C=CC=C1Cl)C1=C(Cl)C=CC=C1Cl)C1=C(Cl)C=CC=C1Cl

Molecular Weight

993.706

Molecular Formula

C45H23Cl9MnN4

Functional Groups

Chloro, Halogenated

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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