meso-Tetra(4-trifluoromethylphenyl) porphine

meso-Tetra(4-trifluoromethylphenyl) porphine CAS: 56420-24-7 MDL:  MFCD28118891

Molecular weight:  886.73 g/mol

Molecular Formula: C₄₈H₂₆F₁₂N₄

CAS Number: 56420-24-7

Storage: Store at room temperature, protect from light.

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis[4-(trifluoromethyl)phenyl]-, 5,10,15,20-Tetrakis[4-(trifluormethyl)phenyl]porphyrin, 5,10,15,20-Tetrakis[4-(trifluoromethyl)phenyl]porphyrin, 5,10,15,20-Tétrakis[4-(trifluorométhyl)phényl]porphyrine,  56420-24-7, Meso-Tetra(4-trifluoromethylphenyl) porphine

Fields of Interest: Synthetic Porphyrins, Fluorinated Porphyrins

Background: meso-Tetra(4-trifluoromethylphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Jin, et al. Fluoroalkylation of porphyrins: Synthesis and reactions of β-fluoroalkyltetraarylporphyrins. Journal of Organic Chemistry, 2003, vol. 68, # 10, p. 3912 – 3917. https://doi.org/10.1021/jo0207269

2.) Remello, et al. Synthesis of water-soluble silicon-porphyrin: Protolytic behaviour of axially coordinated hydroxy groups. Dalton Transactions, 2015, vol. 44, # 46, p. 20011 – 20020. https://doi.org/10.1039/C5DT03654B

3.) Arunkumar, et al. Structural, spectroscopic and electrochemical investigations on fluorinated meso -tetraaryl porphyrins. Journal of Porphyrins and Phthalocyanines, 2017, vol. 21, # 9, p. 622 – 631. https://doi.org/10.1142/S108842461750064X

4.) Bruckner, et al. Stepwise Preparation of meso-Tetraphenyl- and meso-Tetrakis(4-trifluoromethylphenyl)bacteriodilactones and their Zinc(II) and Palladium(II) Complexes. European Journal of Organic Chemistry, 2020, vol. 2020, # 4, p. 475 – 482. https://doi.org/10.1002/ejoc.201901727

5.) Guergueb, et al. CO₂ to CO Electroreduction, Electrocatalytic H₂ Evolution, and Catalytic Degradation of Organic Dyes Using a Co(II) meso-Tetraarylporphyrin. Molecules, 2022, vol. 27, # 5, art. no. 1705. https://doi.org/10.3390/molecules27051705

6.) Sugimura, et al. 20π Antiaromatic Isophlorins without Metallation or Core Modification. European Journal of Organic Chemistry, 2022, vol. 2022, # 46, art. no. E202200747. https://doi.org/10.1002/ejoc.202200747