meso-Tetra(2,6-difluorophenyl) porphine

Product Number: T40436; CAS Number: 104322-39-6

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meso-Tetra(2,6-difluorophenyl) porphine CAS: 104322-39-6 MDL: MFCD00600965

Molecular weight: 758.66 g/mol

Molecular Formula: C44H22F8N4

CAS Number: 104322-39-6

Storage: Store at room temperature, protect from light

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(2,6-difluorophenyl)-, 5,10,15,20-Tetrakis(2,6-difluorophenyl)porphyrin, 5,10,15,20-Tétrakis(2,6-difluorophényl)porphyrine, 5,10,15,20-Tetrakis(2,6-difluorphenyl)porphyrin, 104322-39-6, 2,7,12,17-tetrakis(2,6-difluorophenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.13,?.1?,11.113,1?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene

Field of Interest: Synthetic Porphyrins,

Background: meso-Tetra(2,6-difluorophenyl) porphine is a synthetic porphyrin based specialty chemical.

References: 

1.) Armaut, et al. Photodynamic therapy efficacy enhanced by dynamics: The role of charge transfer and photostability in the selection of photosensitizers. Chemistry – A European Journal, 2014, vol. 20, # 18, p. 5346 – 5357. https://doi.org/10.1002/chem.201304202

2.) Peraira, et al. An insight into solvent-free diimide porphyrin reduction: A versatile approach for meso-aryl hydroporphyrin synthesis. Green Chemistry, 2012, vol. 14, # 6, p. 1666 – 1672. https://doi.org/10.1039/C2GC35126A

3.) Yu, et al. Ruthenium-catalyzed oxidation of the porphyrin β,β-pyrrolic ring: A general and efficient approach to porpholactones. Advanced Synthesis and Catalysis, 2012, vol. 354, # 18, p. 3509 – 3516. https://doi.org/10.1002/adsc.201200720

4.) Cuesta-Aluja, et al. Halogenated meso-phenyl Mn(III) porphyrins as highly efficient catalysts for the synthesis of polycarbonates and cyclic carbonates using carbon dioxide and epoxides. Journal of Molecular Catalysis A: Chemical, 2016, vol. 423, p. 489 – 494. https://doi.org/10.1016/j.molcata.2015.10.025

5.) Henriques, et al. Biologically Inspired and Magnetically Recoverable Copper Porphyrinic Catalysts: A Greener Approach for Oxidation of Hydrocarbons with Molecular Oxygen. Advanced Functional Materials, 2016, vol. 26, # 19, p. 3359 – 3368. https://doi.org/10.1002/adfm.201505405

6.) Dabrowski, et al. New hybrid materials based on halogenated metalloporphyrins for enhanced visible light photocatalysis. RSC Advances, 2015, vol. 5, # 113, p. 93252 – 93261. https://doi.org/10.1039/C5RA19742B

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[104322-39-6]

Purity %

>95%

Smiles

FC1=CC=CC(F)=C1C1=C2NC(C=C/2)=C(/C2=N/C(/C=C2)=C(C2=CC=C(N2)/C(=C2/C=CC1=N/2)C1=C(F)C=CC=C1F)C1=C(F)C=CC=C1F)C1=C(F)C=CC=C1F

Molecular Weight

758.659

Molecular Formula

C44H22F8N4

Functional Groups

fluorine, Fluoro, Halogenated

Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Free Base Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Pyridyl Substituted Porphyrins

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