meso-Tetra(2-nitrophenyl) porphine

meso-Tetra(2-nitrophenyl) porphine CAS: 37116-82-8 MDL: MFCD03427530

Molecular weight: 794.73 g/mol

Molecular Formula: C₄₄H₂₆N₈O₈

CAS Number: 37116-82-8

Storage: Store at room temperature, protect from light

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(2-nitrophenyl)-, 5,10,15,20-Tetrakis(2-nitrophenyl)porphyrin, 5,10,15,20-Tetrakis(2-nitrophenyl)porphyrin, 5,10,15,20-Tétrakis(2-nitrophényl)porphyrine, 37116-82-8, 5,10,15,20-TETRA(2-NITROPHENYL)PORPHYRIN, MFCD03427530

Field of Interest: Synthetic Porphyrins,

Background: meso-Tetra(2-nitrophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

1.) Collman, et al. Picket fence porphyrins. Synthetic models for oxygen binding hemoproteins. J. Am. Chem. Soc. 1975, 97, 6, 1427–1439. https://doi.org/10.1021/ja00839a026

2.) Apfel, et al. Homolytic versus Heterolytic Hydrogen Evolution Reaction Steered by a Steric Effect. Angewandte Chemie – International Edition, 2020, vol. 59, # 23, p. 8941 – 8946. https://doi.org/10.1002/anie.202002311

3.) Das, et al. Iron-Catalyzed Amination of Strong Aliphatic C(sp³)-H Bonds. Journal of the American Chemical Society, 2020, vol. 142, # 38, p. 16211 – 16217. https://doi.org/10.1021/jacs.0c07810

4.) Apfel, et al. Controlling Oxygen Reduction Selectivity through Steric Effects: Electrocatalytic Two-Electron and Four-Electron Oxygen Reduction with Cobalt Porphyrin Atropisomers. Angewandte Chemie – International Edition, 2021, vol. 60, # 23, p. 12742 – 12746. https://doi.org/10.1002/anie.202102523

5.) Nasrollahi, et al. Kinetics and mechanistic studies on the formation and reactivity of high valent MnO porphyrin species: Mono-: ortho or para -substituted porphyrins versus a di- ortho -substituted one. New Journal of Chemistry, 2018, vol. 42, # 3, p. 1806 – 1815. https://doi.org/10.1039/C7NJ04233G

6.) Khvostichenko, et al. Simple heme dimers with strongly cooperative ligand binding. Angewandte Chemie – International Edition, 2007, vol. 46, # 44, p. 8368 – 8370. https://doi.org/10.1002/anie.200702120