meso-Tetra (p-bromophenyl) porphine

meso-Tetra (p-bromophenyl) porphine 5,10,15,20-Tetrakis(4-bromophenyl)-21H,23H-porphine CAS: 29162-73-0 MDL: MFCD02114459

Molecular weight: 930.32 g/mol

Molecular Formula: C₄₄H₂₆Br₄N₄

CAS Number: 29162-73-0

Storage: Store at room temperature, protect from light

Synonyms: 21H,23H-Porphine, 5,10,15,20-tetrakis(4-bromophenyl)-, 5,10,15,20-Tetrakis(4′-bromophenyl)porphyrin, 5,10,15,20-Tetrakis(4-bromophenyl)porphyrin, 5,10,15,20-Tétrakis(4-bromophényl)porphyrine, 5,10,15,20-Tetrakis(4-bromphenyl)porphyrin, MFCD02114459, 2,7,12,17-TETRAKIS(4-BROMOPHENYL)-21,22,23,24-TETRAAZAPENTACYCLO[16.2.1.1(3,6).1(8,11).1(13,16)]TETRACOSA-1,3,5,7,9,11(23),12,14,16,18(21),19-UNDECAENE, 29162-73-0, 5,10,15,20-tetrakis(4-bromophenyl)-21,22-dihydroporphyrin, 5,10,15,20-Tetrakis(4-bromophenyl)-21H,23H-porphine, 5,10,15,20-四(4-溴基苯基)卟啉, meso-Tetra (p-bromophenyl) porphine

Field of Interest: Synthetic Porphyrins, Suzuki Coupling, Covalent Organic Frameworks COFs

Background: meso-Tetra (p-bromophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

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2.) Lv, et al. A Base-Resistant Metalloporphyrin Metal–Organic Framework for C–H Bond Halogenation. J. Am. Chem. Soc. 2017, 139, 1, 211–217. https://doi.org/10.1021/jacs.6b09463

3.) Liang, et al. Porphyrin-based frameworks for oxygen electrocatalysis and catalytic reduction of carbon dioxide. Chem. Soc. Rev., 2021,50, 2540-2581. DOIhttps://doi.org/10.1039/D0CS01482F

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5.) Yuan, et al. Effective and Selective Catalysts for Cinnamaldehyde Hydrogenation: Hydrophobic Hybrids of Metal–Organic Frameworks, Metal Nanoparticles, and Micro- and Mesoporous Polymers. Angewandte Chemie – International Edition, 2018, vol. 57, # 20, p. 5708 – 5713. https://doi.org/10.1002/anie.201801289

6.) Biswal, et al. Nonlinear Optical Switching in Regioregular Porphyrin Covalent Organic Frameworks. Angewandte Chemie – International Edition, 2019, vol. 58, # 21, p. 6896 – 6900. https://doi.org/10.1002/anie.201814412

7.) Lu, et al. Synthesis of a conjugated porous Co(ii) porphyrinylene–ethynylene framework through alkyne metathesis and its catalytic activity study. J. Mater. Chem. A, 2015,3, 4954-4959. https://doi.org/10.1039/C4TA06231K

8.) Liu, et al. Synthesis and photovoltaic properties of polythiophene stars with porphyrin core. Journal of Materials Chemistry, 2010, vol. 20, # 6, p. 1140 – 1146. https://doi.org/10.1039/B916935K

9.) Gao, et al. General and Efficient Synthesis of Arylamino- and Alkylamino-Substituted Diphenylporphyrins and Tetraphenylporphyrins via Palladium-Catalyzed Multiple Amination Reactions. J. Org. Chem. 2003, 68, 16, 6215–6221. https://doi.org/10.1021/jo034576t

10.) Eder, et al. A ruthenium porphyrin-based porous organic polymer for the hydrosilylative reduction of CO₂ to formate. Chemical Communications, 2019, vol. 55, # 50, p. 7195 – 7198. https://doi.org/10.1039/C9CC02273B