meso-Tetra-(3,5-di-t-butylphenyl)porphine

meso-Tetra-(3,5-di-t-butylphenyl)porphine CAS: 89372-90-7 MDL: MFCD01074423

Molecular weight: 1063.59 g/mol

Molecular Formula: C₇₆H₉₄N₄

CAS Number: 89372-90-7

Storage: Store at room temperature, protect from light

Synonyms: 2,7,12,17-Tetrakis(3,5-di-tert-butylphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 2,7,12,17-tetrakis(3,5-di-tert-butylphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1³,?.1?,¹¹.1¹³,¹?]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 21H,23H-Porphine, 5,10,15,20-tetrakis[3,5-bis(1,1-dimethylethyl)phenyl]-, 5,10,15,20-Tetrakis(3,5-di-tert-butylphenyl)porphyrin, 5,10,15,20-Tetrakis[3,5-bis(2-methyl-2-propanyl)phenyl]porphyrin, 5,10,15,20-Tetrakis[3,5-bis(2-methyl-2-propanyl)phenyl]porphyrin, 5,10,15,20-Tétrakis[3,5-bis(2-méthyl-2-propanyl)phényl]porphyrine, 89372-90-7, (1Z,4Z,9Z,15Z)-5,10,15,20-tetrakis(3,5-ditert-butylphenyl)-21,23-dihydroporphyrin, 2,7,12,17-TETRAKIS(3,5-DITERT-BUTYLPHENYL)-21,22,23,24-TETRAAZAPENTACYCLO[16.2.1.1(3,6).1(8,11).1(13,16)]TETRACOSA-1(21),2,4,6,8(23),9,11,13,15,17,19-UNDECAENE, 2,7,12,17-tetrakis(3,5-ditert-butylphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1(21),2,4,6,8(23),9,11,13,15,17,19-undecaene, 2,7,12,17-tetrakis(3,5-di-tert-butylphenyl)-21,22,23,24-tetraazapentacyclo[16.2.1.1^3,6.1^8,11.1^13,16]tetracosa-1,3,5,7,9,11(23),12,14,16,18(21),19-undecaene, 5,10,15,20-Tetrakis(3,5-bis(1,1-dimethylethyl)phenyl)-21H,23H-porphine, 5,10,15,20-TETRAKIS(3,5-BIS(TERT-BUTYL)PHENYL)PORPHYRIN, 5,10,15,20-tetrakis(3,5-di-t-butyl phenyl)porphyrin, 5,10,15,20-Tetrakis(3,5-di-tert.-butylphenyl)porphyrin, 5,10,15,20-tetrakis(3,5-ditert-butylphenyl)-21,22-dihydroporphyrin, 5,10,15,20-tetrakis-(3,5-di-tert-butylphenyl)porphyrin, 5,10,15,20-Tetrakis[3,5-bis(1,1-dimethylethyl)phenyl]-21H,23H-porphine, meso-tetra-(3,5-di-t-butylphenyl)porphine. MFCD01074423, MolPort-008-420-936, SCHEMBL2064907, tetra(3,5-di-t-butylphenyl)porphin

Field of Interest: Synthetic Porphyrins, Dye Sensitized Solar Cells DSSCs,

Background: meso-Tetra-(3,5-di-t-butylphenyl)porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References: 

1.) Hampel, et al. Oxidative Cyclodehydrogenation Reactions with Tetraarylporphyrins. European Journal of Organic Chemistry, 2020, vol. 2020, # 43, p. 6758 – 6762. https://doi.org/10.1002/ejoc.202001174

2.) Ladomenou, et al. Ru(II) porphyrins as sensitizers for DSSCs: Axial vs. peripheral carboxylate anchoring group. Journal of Porphyrins and Phthalocyanines, 2019, vol. 23, # 7-8, p. 870 – 880. https://doi.org/10.1142/S108842461950072X

3.) Weber, et al. Cunning metal core: Efficiency/stability dilemma in metallated porphyrin based light-emitting electrochemical cells. Dalton Transactions, 2016, vol. 45, # 34, p. 13284 – 13288. https://doi.org/10.1039/C6DT02293F

4.) Lee, et al. Synthetically tuneable biomimetic artificial photosynthetic reaction centres that closely resemble the natural system in purple bacteria. Chemical Science, 2016, vol. 7, # 10, p. 6534 – 6550. https://doi.org/10.1039/C6SC01076H

5.) Di Carlo, et al. Light-Induced Regiospecific Bromination of meso-Tetra(3,5-di-tert-butylphenyl)Porphyrin on 2,12 β-Pyrrolic Positions. Journal of Organic Chemistry, 2015, vol. 80, # 10, p. 4973 – 4980. https://doi.org/10.1021/acs.joc.5b00367

6.) Jasieniak, et al. Characterization of a porphyrin-containing dye-sensitized solar cell. Journal of Physical Chemistry B, 2004, vol. 108, # 34, p. 12962 – 12971. https://doi.org/10.1021/jp048073i

7.) Di Carlo, et al. Tetraaryl Zn^II porphyrinates substituted at β-pyrrolic positions as sensitizers in dye-sensitized solar cells: A comparison with meso-disubstituted push-pull Zn^II porphyrinates .Chemistry – A European Journal, 2013, vol. 19, # 32, p. 10723 – 10740. https://doi.org/10.1002/chem.201300219

8.) Flamigni, et al. Switching of electron-to energy-transfer by selective excitation of different chromophores in arrays based on porphyrins and a polypyridyl iridium complex. Journal of Physical Chemistry B, 2002, vol. 106, # 26, p. 6663 – 6671.  https://doi.org/10.1021/jp025509q

9.) Eng, et al. Triplet photophysics of gold(III) porphyrins. Journal of Physical Chemistry A, 2005, vol. 109, # 9, p. 1776 – 1784. J. Phys. Chem. A 2005, 109, 9, 1776–1784. https://pubs.acs.org/doi/10.1021/jp0449399

10.) Tamiaki, et al. Induced circular dichroism by complexation of gadolinium(III) porphyrinates with chiral amino acids and dipeptides: Effects of axial β-diketonate ligands on chirality sensing and recognition. Tetrahedron, 2003, vol. 59, # 52, p. 10477 – 10483. https://doi.org/10.1016/j.tet.2003.08.069