meso-Tetra (2-carboxyphenyl) porphine

Product Number: T40860; CAS Number: 70152-55-5

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meso-Tetra (2-carboxyphenyl) porphine CAS: 70152-55-5 MDL: MFCD22377454

Molecular weight: 790.77 g/mol

Molecular Formula: C48H30N4O8

CAS Number: 70152-55-5

Storage: Store at room temperature, protect from light.

Synonyms: meso-Tetra (2-carboxyphenyl) porphine, 5,10, 15,20-tetrakis(carboxyphenyl)porphyrin, 70152-55-5, MFCD22377454

Fields of Interest: Synthetic Porphyrins, Proton Relays, MOF’s

Background: meso-Tetra (2-carboxyphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. meso-Tetra (2-carboxyphenyl) porphine is sold as a mixture of atropisomers.

References:

1.) Leondiadis, et al. 5,10,15,20-Tetrakis(.alpha.,.alpha.,.alpha.,.alpha.-o-(N-tert-butyl-carbamoyl)phenyl)porphyrin: synthesis and redox properties of zinc(II) and copper(II) complexes.  J. Org. Chem. 1989, 54, 26, 6135–6138. https://doi.org/10.1021/jo00287a034

2.) Nishino, et al. Induced circular dichroism of atropisomeric porphyrins by combined amino acid residues. J. Chem. Soc., Chem. Commun., 1992, 692-694. https://doi.org/10.1039/D2CC04230D

3.) Carver, et al. Electrocatalytic Oxygen Reduction by Iron Tetra-arylporphyrins Bearing Pendant Proton Relays. J. Am. Chem. Soc. 2012, 134, 12, 5444–5447. https://doi.org/10.1021/ja211987f

4.) Dai, et al. Ultrathin MOF nanosheet-based resistive sensors for highly sensitive detection of methanol. Chem. Commun., 2022,58, 11543-11546. https://doi.org/10.1039/D2CC04230D

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[70152-55-5]

Purity %

>95%

Smiles

OC(=O)C1=CC=CC=C1C1=C2NC(C=C/2)=C(/C2=N/C(/C=C2)=C(C2=CC=C(N2)/C(=C2/C=CC1=N/2)C1=CC=CC=C1C(O)=O)C1=CC=CC=C1C(O)=O)C1=CC=CC=C1C(O)=O

Molecular Weight

790.774

Molecular Formula

C48H30N4O8

Functional Groups

Carboxy, Carboxylic Acid

Porphyrin Family

A4 Porphyrins, Free Base Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Carboxy Substituted Porphyrins, Carboxy-Phenyl Substituted Porphyrins, Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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