Gd(III) meso-Tetra(pentafluorophenyl)porphine 2,4-pentane dionate

Catalog#: T40381; CAS Number: 212851-23-5

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Gd(III) meso-Tetra(pentafluorophenyl)porphine 2,4-pentane dionate CAS: 212851-23-5 MDL: MFCD32267995

Molecular weight: 1228.89 g/mol

Molecular Formula: C49H15F20GdN4O2

CAS Number: 212851-23-5

Storage: Store at room temperature, protect from light.

Synonyms: Gd(III) meso-Tetra(pentafluorophenyl)porphine 2,4-pentane dionate, GdTFPP acetylacetonate, 212851-23-5, MFCD32267995

Fields of Interest: Synthetic Porphyrins, Lanthanide Porphyrins, NIR Luminescence

Background: Gd(III) meso-Tetra(pentafluorophenyl)porphine 2,4-pentane dionate is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Gd(III) porphyrins have unique luminescence and other photophysical properties.

References:

1.) Ke, et al. Gadolinium(III) Porpholactones as Efficient and Robust Singlet Oxygen Photosensitizers. Chemistry A European Journal. Volume 22, Issue 28, July 4, 2016, Pages 9676-9686. https://doi.org/10.1002/chem.201601517

2.) Kahlil, et al. NIR luminescence of gadolinium porphyrin complexes. Chemical Physics Letters. Volume 435, Issues 1–3, 12 February 2007, Pages 45-49. https://doi.org/10.1016/j.cplett.2006.12.042

3.) Chan, et al. Lanthanide–tetrapyrrole complexes: synthesis, redox chemistry, photophysical properties, and photonic applications. Chem. Soc. Rev., 2021, 50, 12189-12257. 10.1039/C9CS00828D 

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[212851-23-5]

Purity %

>95%

Smiles

CC(=O)C=C(C)[O-].FC1=C(F)C(F)=C(C(F)=C1F)C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Gd+]N23)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F

Molecular Weight

1228.89

Molecular Formula

C49H15F20GdN4O2

Functional Groups

fluorine, Trifluoromethyl

Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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