Fe(III) meso-Tetra(Pentafluorophenyl) Porphine Chloride

Product Number: T41158; CAS Number: 36965-71-6

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Fe(III) meso-Tetra(Pentafluorophenyl) Porphine Chloride CAS: 36965-71-6 MDL: MFCD00012151

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Molecular weight: 1063.827 g/mol

Molecular Formula: C44H8ClF20FeN4

CAS Number: 36965-71-6

Storage: Store at room temperature, protect from light.

Synonyms: 36965-71-6, Chlor[5,10,15,20-tetrakis(pentafluorphenyl)porphyrinato(2-)-κ2N21,N23]eisen, Chloro[5,10,15,20-tetrakis(pentafluorophenyl)porphyrinato(2-)-κ2N21,N23]iron, Chloro[5,10,15,20-tétrakis(pentafluorophényl)porphyrineato(2-)-κ2N21,N23]fer, Iron, chloro[5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-21H,23H-porphinato(2-)-κN21,κN23]-, MFCD00012151, 5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-21H,23H-PORPHINE IRON(III) CHLORIDE, 5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphyrin iron(III) chloride, 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin iron(iii) chloride, 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin iron(III) chloride complex, 

Fields of Interest: Catalysis, Cytochrome P450 mimics, Electrophilic Halogenation, Biomimetic Oxidation

Background: Fe(III) meso-Tetra(Pentafluorophenyl) Porphine Chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Fe(III) meso-Tetra(Pentafluorophenyl) Porphine Chloride is commonly used for biomimetic oxidations.1-5

References:

1.) Balogh-Weiser, et al. Magnetic Nanoparticles with Dual Surface Functions—Efficient Carriers for Metalloporphyrin-Catalyzed Drug Metabolite Synthesis in Batch and Continuous-Flow Reactors. Nanomaterials 2020, 10, 2329. https://doi.org/10.3390/nano10122329

2.) Engbers, et al. Toward Environmentally Benign Electrophilic Chlorinations: From Chloroperoxidase to Bioinspired Isoporphyrins, Inorg. Chem. 2022, 61, 21, 8105–8111. https://doi.org/10.1021/acs.inorgchem.2c00602

3.) Hiroshi, et al. Characterization of High Valent Iron Porphyrin in Catalytic Reaction by Iron(III) Tetrapentafluorophenylporphyrin. Chemistry Letters, 1994, Vol.23, No.8, 1491-1494. https://www.journal.csj.jp/doi/abs/10.1246/cl.1994.1491

4.) Franke, et al. Axial Ligand and Spin-State Influence on the Formation and Reactivity of Hydroperoxo–Iron(III) Porphyrin Complexes. Chemistry, a European Journal.Volume 18, Issue 22, May 29, 2012, Pages 6935-6949. https://doi.org/10.1002/chem.201103036

5.) Pereira, et al. Metalloporphyrins: Bioinspired Oxidation Catalysts. ACS Catal. 2018, 8, 11, 10784–10808. https://doi.org/10.1021/acscatal.8b01871

Categories

Porphyrins
Scaffold/Subcategory

Synthetic Porphyrins
CAS #

[36965-71-6]
Purity %

>95%
Smiles

FC1=C(F)C(F)=C(C(F)=C1F)C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Fe](Cl)N23)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F
Molecular Weight

1063.83
Molecular Formula

C44H8ClF20FeN4
Functional Groups

fluorine, Fluoro
Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives
Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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