Cu(II) meso-Tetra(o-dichlorophenyl) porphine

Product Number: U34557; CAS Number: 135685-21-1

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Cu(II) meso-Tetra(o-dichlorophenyl) porphine CAS: 135685-21-1 MDL: MFCD06227758

Molecular weight: 951.83 g/mol

Molecular Formula: C44H20Cl8CuN4

CAS Number: 135685-21-1

Storage: Store at room temperature, protect from light.

Synonyms: Cu(TDCIPP), Cu(II) meso-Tetra(o-dichlorophenyl) porphine, 135685-21-1, MFCD06227758, Cu(II) meso-Tetra(2,6-dichlorophenyl) porphine,  Cu(II) meso-Tetra(o-dichlorophenyl) porphyrin, Cu(II) meso-Tetra(2,6-dichlorophenyl) porphyrin, meso-tetrakis(o-chlorophenyl)porphyrinato]copper(II)

Fields of Interest: Synthetic Porphyrins, Copper (II) Porphyrins, Click Chemistry

Background: Cu(II) meso-Tetra(o-dichlorophenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Cu(II) meso-Tetra(o-dichlorophenyl) porphine has been used as a catalyst for click chemistry.1

References: 

1.) Sharghi, et al. Immobilization of Porphyrinatocopper Nanoparticles onto Activated Multi-Walled Carbon Nanotubes and a Study of its Catalytic Activity as an Efficient Heterogeneous Catalyst for a Click Approach to the Three-Component Synthesis of 1,2,3-Triazoles in Water. Advanced Synthesis and Catalysis. Volume 351, Issue 14-15, October 2009, Pages 2391-2410. https://doi.org/10.1002/adsc.200900353

2.) Ehlinger, et al. Structure and Apparent Reactivity of the π-Cation Radical Derivatives of Zinc and Copper 5,10,15,20-Tetra(2,6-dichlorophenyl)porphyrinate. Inorg. Chem. 1999, 38, 6, 1316–1321. https://doi.org/10.1021/ic981041n

3.) Cunningham, et al. EPR Spectra, Luminescence Data, and Radiationless Decay Processes of Copper(II) Porphyrins. Inorg. Chem. 1997, 36, 4, 608–613. https://doi.org/10.1021/ic960604x

4.) Li, Y. Solvent effects on photophysical properties of copper and zinc porphyrins. Chin. Sci. Bull. 53, 3615–3619 (2008). https://doi.org/10.1007/s11434-008-0498-8

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[135685-21-1]

Purity %

>95%

Smiles

ClC1=CC=CC(Cl)=C1C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Cu]N23)C1=C(Cl)C=CC=C1Cl)C1=C(Cl)C=CC=C1Cl)C1=C(Cl)C=CC=C1Cl

Molecular Weight

951.826

Molecular Formula

C44H20Cl8CuN4

Functional Groups

Chloro, Halogenated

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Pyridyl Substituted Porphyrins

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