Co(III) meso-Tetra(4-carboxyphenyl) porphine chloride

Product Number: T40144; CAS Number: 121000-08-6

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Co(III) meso-Tetra(4-carboxyphenyl) porphine chloride CAS: 121000-08-6 MDL:

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Molecular weight: 883.14 g/mol

Molecular Formula: C48H28ClCoN4O

CAS Number: 121000-08-6

Storage: Store at room temperature, protect from light

Synonyms: Co(III) meso-Tetra(4-carboxyphenyl) porphine chloride, 121000-08-6

Field of Interest: Metal Organic Frameworks (MOFs), Covalent Organic Frameworks (COFs), synthetic porphyrins

Background: Co(III) meso-Tetra(4-carboxyphenyl) porphine chloride is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Co(III) meso-Tetra(4-carboxyphenyl) porphine chloride has been used for the construction of photocatalytic MOFs and functionalized materials.1-4

References:

1.) Li, et al. Cobalt porphyrin (CoTCPP) advanced visible light response of g-C3N4nanosheets. Sustainable Materials and Technologies. Volume 22, December 2019, e00114. https://doi.org/10.1016/j.susmat.2019.e00114

2.) Bare, et al. Controlling Reduction Potentials of Semiconductor-Supported Molecular Catalysts for Environmental Remediation of Organohalide Pollutants. Environ. Sci. Technol. 2005, 39, 16, 6266–6272. https://doi.org/10.1021/es048058r

3.) Safaei, et al. Photocatalytic activity of nanohybrid Co-TCPP@TiO2/WO3 in aerobic oxidation of alcohols under visible light. J. Mater. Chem. A, 2016,4, 3933-3946. https://doi.org/10.1039/C5TA09357K

4.) Zhang, et al. Two dimensional porphyrin-based metal–organic framework constructed on K4Nb6O17 microflowers for highly efficient charge transfer and photocatalytic hydrogen generation. Applied Surface Science.Volume 599, 15 October 2022, 153922. https://doi.org/10.1016/j.apsusc.2022.153922

Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[121000-08-6]

Purity %

>95%

Smiles

OC(=O)C1=CC=C(C=C1)C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Co](Cl)N23)C1=CC=C(C=C1)C(O)=O)C1=CC=C(C=C1)C(O)=O)C1=CC=C(C=C1)C(O)=O

Molecular Weight

883.144

Molecular Formula

C48H28ClCoN4O8

Functional Groups

Carboxy, Carboxylic Acid

Porphyrin Family

A4 Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Carboxy Substituted Porphyrins, Carboxy-Phenyl Substituted Porphyrins, Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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