Co(II) meso-Tetra (Pentafluorophenyl) porphine

Product Number: T11563; CAS Number: 52242-06-5

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Co(II) meso-Tetra (Pentafluorophenyl) porphine CAS: 52242-06-5 MDL: MFCD09038961

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Molecular weight: 1031.462 g/mol

Molecular Formula: C44H8CoF20N4

CAS Number: 52242-06-5

Storage: Store at room temperature, protect from light

Synonyms: 21H,22H-Porphine, 5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)-, cobalt(2+) salt (1:1), 5,10,15,20-Tétrakis(pentafluorophényl)porphine-21,22-diide de cobalt(2+), Cobalt(2+) 5,10,15,20-tetrakis(pentafluorophenyl)porphine-21,22-diide, Cobalt(2+)-5,10,15,20-tetrakis(pentafluorphenyl)porphin-21,22-diid, 52242-06-5, Co(II) meso-Tetra (Pentafluorophenyl) porphine, MFCD09038961

Field of Interest: Catalysis, Fluorinated Porphyrins, Synthetic Porphyrins,

Background: Co(II) meso-Tetraphenylporphine (contains 1-3% chlorin) is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.

References:

1.) Behar, et al. Cobalt Porphyrin Catalyzed Reduction of CO2. Radiation Chemical, Photochemical, and Electrochemical Studies. J. Phys. Chem. A 1998, 102, 17, 2870–2877. https://doi.org/10.1021/jp9807017

2.) Liu, et al. Single-Walled Carbon Nanotube/Metalloporphyrin Composites for the Chemiresistive Detection of Amines and Meat Spoilage. Angew. Chemie. Int. Ed. Volume 54, Issue 22, May 26, 2015, Pages 6554-6557. https://doi.org/10.1002/anie.201501434

3.) Sun, et al. Slow Electron Transfer Rates for Fluorinated Cobalt Porphyrins:  Electronic and Conformational Factors Modulating Metalloporphyrin ET. Inorg. Chem. 2003, 42, 19, 6032–6040. https://doi.org/10.1021/ic034705o

4.) Zhang, et al. Co-Catalyzed Transannulation of Pyridotriazoles with Isothiocyanates and Xanthate Esters. Org. Lett. 2020, 22, 21, 8500–8504. https://doi.org/10.1021/acs.orglett.0c03099

5.) Lei, et al. First-row transition metal porphyrins for electrocatalytic hydrogen evolution — a SPP/JPP Young Investigator Award paper. Journal of Porphyrins and Phthalocyanines. Vol. 24, No. 11n12, pp. 1361-1371 (2020). https://doi.org/10.1142/S1088424620500157

6.) Lei, et al. Significantly boosted oxygen electrocatalysis with cooperation between cobalt and iron porphyrins. Dalton Trans., 2021,50, 5120-5123. https://doi.org/10.1039/D1DT00441G

Categories

Porphyrins
Metal

Cobalt Porphyrins
Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives
Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins
Functional Groups

fluorine, Fluoro
Purity %

>95%
Molecular Formula

C44H8CoF20N4
Molecular Weight

1031.46
CAS #

52242-06-5

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