Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine

Product Number: T11814; CAS Number: 100165-82-0



Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine CAS: 100165-82-0 MDL: MFCD32643951

Molecular weight: 839.97 g/mol

Molecular Formula: C56H52CoN4

CAS Number: 100165-82-0

Storage: Store at room temperature, protect from light.

Synonyms: Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine, 100165-82-0, TMP-Co(II), MFCD32643951

Fields of Interest: Synthetic Porphyrins, Catalysis, C-H Amination, Living Radical Polymerization

Background: Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a catalyst for the intramolecular ring closing C-H amination of azides.1 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine was used as a catalyst for intermolecular C-H amination using bromamine T.2 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine has been investigated as a catalyst for living radical polymerization.3-5 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a catalyst for the C-H arylation of benzene.6


1.) Kuijpers, et al. Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C−H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles. Chemistry, a European Journal. Volume 23, Issue 33, June 12, 2017, Pages 7945-7952.

2.) Harden, et al. Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source. Chem. Commun., 2007, 4644-4646.



Porphyrin Family

A4 Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

Functional Groups


Purity %


Molecular Formula


Molecular Weight



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