Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine CAS: 100165-82-0 MDL: MFCD32643951
Molecular weight: 839.97 g/mol
Molecular Formula:Â C56H52CoN4
CAS Number:Â 100165-82-0
Storage:Â Store at room temperature, protect from light.
Synonyms: Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine, 100165-82-0, TMP-Co(II), MFCD32643951
Fields of Interest: Synthetic Porphyrins, Catalysis, C-H Amination, Living Radical Polymerization
Background: Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a catalyst for the intramolecular ring closing C-H amination of azides.1 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine was used as a catalyst for intermolecular C-H amination using bromamine T.2 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine has been investigated as a catalyst for living radical polymerization.3-5 Co(II) meso-Tetra (2,4,6-trimethylphenyl) porphine is a catalyst for the C-H arylation of benzene.6
References:
1.) Kuijpers, et al. Cobalt-Porphyrin-Catalysed Intramolecular Ring-Closing C−H Amination of Aliphatic Azides: A Nitrene-Radical Approach to Saturated Heterocycles. Chemistry, a European Journal. Volume 23, Issue 33, June 12, 2017, Pages 7945-7952. https://doi.org/10.1002/chem.201700358
2.) Harden, et al. Cobalt-catalyzed intermolecular C–H amination with bromamine-T as nitrene source. Chem. Commun., 2007, 4644-4646.https://doi.org/10.1039/B710677G
