Au(III) meso-Tetraphenylporphine chloride CAS: 15695-27-9 MDL: MFCD32268009
Molecular weight:Â 845.14Â g/mol
Molecular Formula:Â C44H28AuClN4
CAS Number:Â 15695-27-9
Storage: Store at room temperature, protect from light
Synonyms: Au(III) meso-Tetraphenylporphine chloride, 15695-27-9, MFCD32268009, Gold (III) meso-Tetraphenylporphine Chloride, Gold (III) meso-Tetraphenylporphyrin Chloride, Au(III)TPPCl, AuTPPCl
Field of Interest:Â Catalysis, Synthetic Porphyrins,
Background: Au(III) meso-Tetraphenylporphine chloride (contains 1-3% chlorin) is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Au(III) meso-Tetraphenylporphine chloride is active catalyst for the selective cycloisomerization of allenones.1-2
References:
1.) Zhou, et al. Gold(III) Porphyrin-Catalyzed Cycloisomerization of Allenones. Org. Lett. 2006, 8, 2, 325–328. https://doi.org/10.1021/ol052696c
2.) Nijamudheen, et al. Why Does Gold(III) Porphyrin Act as a Selective Catalyst in the Cycloisomerization of Allenones? J. Phys. Chem. C 2011, 115, 5, 2187–2195. https://doi.org/10.1021/jp1101384
3.) Müllegger, et al. Spectroscopic STM Studies of Single Gold(III) Porphyrin Molecules. J. Am. Chem. Soc. 2009, 131, 49, 17740–17741. https://doi.org/10.1021/ja908157j
