Au(III) meso-Tetraphenylporphine chloride

Product Number: T14968; CAS Number: 15695-27-9

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Au(III) meso-Tetraphenylporphine chloride CAS: 15695-27-9 MDL: MFCD32268009

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Molecular weight: 845.14 g/mol

Molecular Formula: C44H28AuClN4

CAS Number: 15695-27-9

Storage: Store at room temperature, protect from light

Synonyms: Au(III) meso-Tetraphenylporphine chloride, 15695-27-9, MFCD32268009, Gold (III) meso-Tetraphenylporphine Chloride, Gold (III) meso-Tetraphenylporphyrin Chloride, Au(III)TPPCl, AuTPPCl

Field of Interest: Catalysis, Synthetic Porphyrins,

Background: Au(III) meso-Tetraphenylporphine chloride (contains 1-3% chlorin) is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals. Au(III) meso-Tetraphenylporphine chloride is active catalyst for the selective cycloisomerization of allenones.1-2

References:

1.) Zhou, et al. Gold(III) Porphyrin-Catalyzed Cycloisomerization of Allenones. Org. Lett. 2006, 8, 2, 325–328. https://doi.org/10.1021/ol052696c

2.) Nijamudheen, et al. Why Does Gold(III) Porphyrin Act as a Selective Catalyst in the Cycloisomerization of Allenones? J. Phys. Chem. C 2011, 115, 5, 2187–2195. https://doi.org/10.1021/jp1101384

3.) Müllegger, et al. Spectroscopic STM Studies of Single Gold(III) Porphyrin Molecules. J. Am. Chem. Soc. 2009, 131, 49, 17740–17741. https://doi.org/10.1021/ja908157j

Categories

Porphyrins
Scaffold/Subcategory

Synthetic Porphyrins
CAS #

[15695-27-9]
Purity %

>95%
Smiles

Cl[Au]1N2C3=CC=C2C(C2=CC=CC=C2)=C2C=CC(=N2)/C(C2=CC=CC=C2)=C2/C=CC(N12)=C(C1=NC(C=C1)=C/3C1=CC=CC=C1)C1=CC=CC=C1
Molecular Weight

845.139
Molecular Formula

C44H28AuClN4
Porphyrin Family

A4 Porphyrins, Metallo Porphyrins
Porphyrin Substitution

Meso-Substituted Porphyrins

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