Ag(II) meso-Tetraphenylporphine CAS: 14641-64-6 MDL: MFCD02114469
Molecular weight: 720.588 g/mol
Molecular Formula:Â C44H28AgN4
CAS Number: 14641-64-6
Storage:Â Store at room temperature, protect from light.
Synonyms: [5,10,15,20-Tetraph
Fields of Interest: Synthetic Porphyrins, Silver Porphyrins,
Background: Ag(II) meso-Tetraphenylporphine is a synthetic porphyrin specialty chemical manufactured by Frontier Specialty Chemicals.
References:
1.) Scheidt, et al. Crystal and molecular structure of the silver(II) and zinc(II) derivatives of meso-tetraphenylporphyrin. An exploration of crystal-packing effects on bond distance. Inorg. Chem. 1986, 25, 6, 795–799. https://doi.org/10.1021/ic00226a014
2.) Kadish, et al. A reinvestigation of silver porphyrin electrochemistry. Reactions of silver(III), silver(II), and silver(I). Inorg. Chem. 1986, 25, 18, 3236–3242. https://doi.org/10.1021/ic00238a029
3.) Goziela, et al. Solution characterization of copper(II) and silver(II) porphyrins and the one-electron oxidation products by nuclear magnetic resonance spectroscopy. J. Am. Chem. Soc. 1986, 108, 9, 2237–2243. https://doi.org/10.1021/ja00269a019
4.) Milgrom, et al. Residual paramagnetism in silver(III) metalloporphyrin complexes. J. Chem. Soc., Chem. Commun., 1988, 576-578. https://doi.org/10.1039/C39880000576
5.) Zhang, et al. Reaction of metallotetraphenylporphyrins on hydroxyl-modified silver colloid and Ag2O colloid by surface-enhanced Raman scattering. Spectrochimica Acta Part A: Molecular and Biomolecular Spectroscopy. Volume 57, Issue 13, November 2001, Pages 2599-2605.
6.) Hu, et al. Saturable absorption behavior of (5,10,15,20-tetraphenylporphyrinato)-silver crystal thin film at wavelength 532 nm. Journal of Porphyrins and Phthalocyanines. Vol. 25, No. 01, pp. 19-23 (2021)
