2,2′-Dipyrromethane

2,2′-Dipyrromethane CAS: 21211-65-4 MDL: MFCD03931560

SDS

Sizes Available:  1 g, 5 g, 10g, 25 g and larger sizes available

Molecular weight: 146.189 g/mol

Molecular Formula: C₉H₁₀N₂                             

CAS Number: 21211-65-4

Storage: Store at –20 °C, under Argon

Synonyms: 1H-Pyrrole, 2,2′-methylenebis- , 2,2′-Dipyrrolylmethane, 2,2′-Methylenbis(1H-pyrrol), 2,2′-Methylenebis(1H-pyrrole), 2,2′-Méthylènebis(1H-pyrrole), 21211-65-4, di(1H-pyrrol-2-yl)methane, dipyrrolylmethane, dipyrromethane, dipyrrylmethane, [21211-65-4], 124440, 2-(1H-pyrrol-2-ylmethyl)-1H-pyrrole, 2,2-dipyrrolylmethane, 2,2′-Dipyrrolylmethane, 2,2′-Dipyrrolylmethane, Dipyrromethane, 2,2′-Dipyrromethane, 2,2′-methanediylbis(1H-pyrrole), 2-[(1H-pyrrol-2-yl)methyl]-1H-pyrrole, 5,10-dihydrodipyrrin, di-2-pyrrolylmethane, GS-5607, MFCD03931560, pyrromethane

Field of Interest: Porphyrin Building Blocks

Background: 2,2′-Dipyrromethane is a synthetic porphyrin building block specialty chemical manufactured by Frontier Specialty Chemicals. 2,2′-Dipyrromethane is useful for the synthesis of porphyrins and related compounds. 2,2′-Dipyrromethane was used for the synthesis of 5,15-diaryl porphyrins.^1-4

References:

1.) Banfi, et al. Comparison between 5,10,15,20-Tetraaryl- and 5,15-Diarylporphyrins as Photosensitizers:  Synthesis, Photodynamic Activity, and Quantitative Structure−Activity Relationship Modeling.  J. Med. Chem. 2006, 49, 11, 3293–3304. https://doi.org/10.1021/jm050997m

2.) Goncalves, et al. Synthesis and G-quadruplex binding studies of new 4-N-methylpyridinium porphyrins. Org. Biomol. Chem., 2006,4, 3337-3342. https://doi.org/10.1039/B608494J

3.) Vybornyi, et al. Assembling Multiporphyrin Stacks Inside the DNA Double Helix. Bioconjugate Chem. 2014, 25, 10, 1785–1793. https://doi.org/10.1021/bc500297e

4.) Boudiaf, et al. Stable isoporphyrin copolymer: Electrochemical mechanism and behavior and photovoltaic properties. Electrochimica Acta. Volume 309, 20 June 2019, Pages 432-449. https://doi.org/10.1016/j.electacta.2019.04.050