1 g (PdT975)

PdT7975

Technical Data Sheet 

CAS: 72076-09-6 MDL: MFCD01320999

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Pd(II) meso-Tetra(pentafluorophenyl)porphine 5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II) CAS: 72076-09-6 MDL: MFCD01320999

Field of Interest: Synthetic Porphyrins, Oxygen Sensor, Photostable

Molecular weight: 1078.96 g/mol

Molecular Formula: C44H8F20N4Pd                       

CAS Number:  72076-09-6

Storage:   Store at–20 °C, under dry conditions.

Synonyms:   Pd(II) meso-Tetra(pentafluorophenyl)porphine,  5,10,15,20-TETRAKIS(PENTAFLUOROPHENYL)-2,  5,10,15,20-Tetrakis(pentafluorophenyl)-21H,23H-porphine palladium(II)

Background: Pd(II) meso-Tetra(pentafluorophenyl)porphine is a synthetic porphyrin based fine chemical  that is a photostable oxygen sensor with stability due to the fluorine functional groups. 1,2   The catalytic properties of iron complexes are useful for epoxidation of olefins while magnesium complexes are found useful in pressure sensitive paints. 3,4

 

References:   1)  Yeh, Tai-Sheng; Chu, Chen-Shane; Lo, Yu-Lung, Highly sensitive optical fiber oxygen sensor using Pt(II) complex embedded in sol-gel matrices , Sensors and Actuators, B: Chemical (2006), 119(2), 701-707.  2)  Ghosh, Abhik, Substituent Effects on Valence Ionization Potentials of Free Base Porphyrins: A Local Density Functional Study, Journal of the American Chemical Society (1995), 117(16), 4691-9.  3)  Nam, Wonwoo; Lee, Ha J.; Oh, So-Young; Kim, Cheal; Jang, Ho G., First success of catalytic epoxidation of olefins by an electron-rich iron(III) porphyrin complex and H2O2: imidazole effect on the activation of H2O2 by iron porphyrin complexes in aprotic solvent, Journal of Inorganic Biochemistry (2000), 80(3-4), 219-225.  4) Khalil, Gamal E.; Costin, Colin; Crafton, Jim; Jones, Grant; Grenoble, Severin; Gouterman, Martin; Callis, James B.; Dalton, Larry R., Dual-luminophor pressure-sensitive paint I. Ratio of reference to sensor giving a small temperature dependency, Sensors and Actuators, B: Chemical (2004), 97(1), 13-21.

Weight 1 g
Categories

Porphyrins

Scaffold/Subcategory

Synthetic Porphyrins

CAS #

[72076-09-6]

Purity %

>95%

Smiles

FC1=C(F)C(F)=C(C(F)=C1F)C1=C2C=CC(=N2)/C(=C2/C=CC3=C(C4=NC(C=C4)=C(/C4=CC=C1N4[Pd]N23)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F)C1=C(F)C(F)=C(F)C(F)=C1F

Molecular Weight

1078.95

Molecular Formula

C44H8F20N4Pd

Functional Groups

fluorine, Fluoro

Porphyrin Family

A4 Porphyrins, Fluorinated Porphyrins, Metallo Porphyrins, Tetra-Phenyl Porphine Derivatives

Porphyrin Substitution

Meso-Substituted Porphyrins, Phenyl Substituted Porphyrins

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